通过电化学和过渡金属的协同催化,推进烯烃向新 C-C 键的选择性转化

IF 2.1 3区 化学 Q2 CHEMISTRY, ORGANIC Tetrahedron Pub Date : 2024-10-28 DOI:10.1016/j.tet.2024.134330
ChunXiao Nong, Yi Jin
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引用次数: 0

摘要

本文旨在全面回顾近年来,尤其是2018年以来,通过电化学和过渡金属催化协同作用选择性形成烯烃C-C键的研究进展。具体而言,我们将重点关注电化学和过渡金属的联合催化如何实现对化学、立体选择性和区域选择性结果的精确控制,并深入探讨其背后的反应机理。通过总结关键科学发现和技术突破,本文旨在为相关领域的研究人员提供参考指南,并为该领域的未来趋势和潜在应用提供见解。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Advancements in the selective transformation of olefins to new C–C bonds through cooperative catalysis involving electrochemistry and transition metals
This article aims to comprehensively review the research progress in the selective C–C bond formation of olefins through the synergistic action of electrochemistry and transition metal catalysis in recent years, particularly since 2018. Specifically, we will focus on how the combined catalysis of electrochemistry and transition metals achieves precise control over chemical, stereoselective, and regioselective outcomes, and delve deeply into the underlying reaction mechanisms. By summarizing key scientific discoveries and technological breakthroughs, this article aims to provide a reference guide for researchers in related fields and offer insights into future trends and potential applications in this domain.
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来源期刊
Tetrahedron
Tetrahedron 化学-有机化学
CiteScore
3.90
自引率
4.80%
发文量
439
审稿时长
34 days
期刊介绍: Tetrahedron publishes full accounts of research having outstanding significance in the broad field of organic chemistry and its related disciplines, such as organic materials and bio-organic chemistry. Regular papers in Tetrahedron are expected to represent detailed accounts of an original study having substantially greater scope and details than that found in a communication, as published in Tetrahedron Letters. Tetrahedron also publishes thematic collections of papers as special issues and ''Reports'', commissioned in-depth reviews providing a comprehensive overview of a research area.
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Contents continued Graphical abstract TOC Graphical abstract TOC Editorial Board Synthesis of dendritic self-immolative molecules triggered by reactive electrophilic alkylating agents: Assessment for colorimetric disclosure of such agents
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