{"title":"喜马拉雅龙舌兰纤维/GO 涂层粉煤灰混合聚丙烯复合材料的力学、热学和形态学分析。","authors":"Piyush Kumar, Hariome Sharan Gupta, Manjinder Singh, Arjun S Chaudhari, Atul Kumar Maurya, Gaurav Manik","doi":"10.1002/chem.202402393","DOIUrl":null,"url":null,"abstract":"<p><p>Composites containing two different types of reinforcements offer a wide range of possibilities and synergistic properties. This study investigates the hybridization effect of chemically active fly ash (FA) (5 wt.%) on the composites made from alkali (1 wt.%) - APTES silane (2 wt.%) treated Himalayan agave fibers (HAF) (25 wt.%) and polypropylene (PP). Prior to FA activation, the planetary ball mill was used to suitably reduce the particle size of the FA with was confirmed by the dynamic light scattering approach. Secondary reinforcement FA was modified with APTES silane (1 wt.%), followed by treatment with graphene oxide (GO) (0.5, 0.75, and 1 wt.%). The highest tensile strength of 40.47 MPa and modulus of 1.49 GPa were observed for the hybrid composites fabricated from 0.75 and 1.0 wt.% GO treated fly ash. Interestingly, this trend differed for flexural properties, and the highest flexural strength of 53.52 MPa was demonstrated by 0.5 wt.% GO treated FA hybrid composite. Thermal characterization revealed that addition of fiber increased crystallinity but decreased thermal stability, whereas a good wettability of the fiber and FA in matrix was demonstrated through morphological characterization.</p>","PeriodicalId":144,"journal":{"name":"Chemistry - A European Journal","volume":null,"pages":null},"PeriodicalIF":3.9000,"publicationDate":"2024-11-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Mechanical, Thermal, and Morphological Analysis of Himalayan Agave Fiber /GO Coated Fly Ash Hybrid Polypropylene Composites.\",\"authors\":\"Piyush Kumar, Hariome Sharan Gupta, Manjinder Singh, Arjun S Chaudhari, Atul Kumar Maurya, Gaurav Manik\",\"doi\":\"10.1002/chem.202402393\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Composites containing two different types of reinforcements offer a wide range of possibilities and synergistic properties. This study investigates the hybridization effect of chemically active fly ash (FA) (5 wt.%) on the composites made from alkali (1 wt.%) - APTES silane (2 wt.%) treated Himalayan agave fibers (HAF) (25 wt.%) and polypropylene (PP). Prior to FA activation, the planetary ball mill was used to suitably reduce the particle size of the FA with was confirmed by the dynamic light scattering approach. Secondary reinforcement FA was modified with APTES silane (1 wt.%), followed by treatment with graphene oxide (GO) (0.5, 0.75, and 1 wt.%). The highest tensile strength of 40.47 MPa and modulus of 1.49 GPa were observed for the hybrid composites fabricated from 0.75 and 1.0 wt.% GO treated fly ash. Interestingly, this trend differed for flexural properties, and the highest flexural strength of 53.52 MPa was demonstrated by 0.5 wt.% GO treated FA hybrid composite. Thermal characterization revealed that addition of fiber increased crystallinity but decreased thermal stability, whereas a good wettability of the fiber and FA in matrix was demonstrated through morphological characterization.</p>\",\"PeriodicalId\":144,\"journal\":{\"name\":\"Chemistry - A European Journal\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.9000,\"publicationDate\":\"2024-11-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemistry - A European Journal\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1002/chem.202402393\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry - A European Journal","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1002/chem.202402393","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
含有两种不同类型增强材料的复合材料具有广泛的可能性和协同特性。本研究探讨了化学活性粉煤灰(FA)(5 wt.%)对由碱(1 wt.%)- APTES 硅烷(2 wt.%)处理过的喜马拉雅龙舌兰纤维(HAF)(25 wt.%)和聚丙烯(PP)制成的复合材料的杂化效应。在 FA 活化之前,使用行星球磨机适当减小 FA 的粒径,并通过动态光散射法进行确认。用 APTES 硅烷(1 wt.%)对二级增强 FA 进行改性,然后用氧化石墨烯(GO)(0.5、0.75 和 1 wt.%)进行处理。经 0.75 和 1.0 wt.% GO 处理的粉煤灰制成的混合复合材料的拉伸强度最高,达到 40.47 MPa,模量最高,达到 1.49 GPa。有趣的是,这种趋势在抗弯特性方面有所不同,经 0.5 wt.% GO 处理的 FA 混合复合材料的抗弯强度最高,达到 53.52 MPa。热表征显示,纤维的加入增加了结晶度,但降低了热稳定性,而纤维和 FA 在基体中的良好润湿性则通过形态表征得到了证明。
Mechanical, Thermal, and Morphological Analysis of Himalayan Agave Fiber /GO Coated Fly Ash Hybrid Polypropylene Composites.
Composites containing two different types of reinforcements offer a wide range of possibilities and synergistic properties. This study investigates the hybridization effect of chemically active fly ash (FA) (5 wt.%) on the composites made from alkali (1 wt.%) - APTES silane (2 wt.%) treated Himalayan agave fibers (HAF) (25 wt.%) and polypropylene (PP). Prior to FA activation, the planetary ball mill was used to suitably reduce the particle size of the FA with was confirmed by the dynamic light scattering approach. Secondary reinforcement FA was modified with APTES silane (1 wt.%), followed by treatment with graphene oxide (GO) (0.5, 0.75, and 1 wt.%). The highest tensile strength of 40.47 MPa and modulus of 1.49 GPa were observed for the hybrid composites fabricated from 0.75 and 1.0 wt.% GO treated fly ash. Interestingly, this trend differed for flexural properties, and the highest flexural strength of 53.52 MPa was demonstrated by 0.5 wt.% GO treated FA hybrid composite. Thermal characterization revealed that addition of fiber increased crystallinity but decreased thermal stability, whereas a good wettability of the fiber and FA in matrix was demonstrated through morphological characterization.
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