{"title":"二氯(冠醚)镧系(III)四氯铝酸盐络合物","authors":"","doi":"10.1016/j.poly.2024.117270","DOIUrl":null,"url":null,"abstract":"<div><div>Reactions between LnCl<sub>3</sub>, AlCl<sub>3</sub> and a crown ether (18-crown-6 and dibenzo18-crown-6) in MeCN have led to the isolation of four new lanthanoid halide crown ether complexes, [PrCl(μ-Cl)(18-crown-6)]<sub>2</sub>[AlCl<sub>4</sub>]<sub>2</sub>·2MeCN (<strong>1</strong>), [YbCl<sub>2</sub>(18-crown-6)][AlCl<sub>4</sub>]·MeCN (<strong>2</strong>), and [LnCl(μ-Cl)(dibenzo18-crown-6)}<sub>2</sub>][AlCl<sub>4</sub>]<sub>2</sub>·6.5MeCN (Ln = La, <strong>3</strong>, Pr, <strong>4</strong>). <strong>1</strong> was also obtained by unexpected halide transfer on addition of 18-crown-6 (18C6) to MeCN solutions of [Pr(MeCN)<sub>9</sub>][AlCl<sub>4</sub>]<sub>3</sub>. Complexes <strong>1</strong>, <strong>3</strong> and <strong>4</strong> have dinuclear chloride-bridged nine-coordinate cations, and <strong>2</strong> has an eight coordinate mononuclear cation.</div></div>","PeriodicalId":20278,"journal":{"name":"Polyhedron","volume":null,"pages":null},"PeriodicalIF":2.4000,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Dichlorido(crown ether)lanthanoid(III) tetrachloroaluminate complexes\",\"authors\":\"\",\"doi\":\"10.1016/j.poly.2024.117270\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Reactions between LnCl<sub>3</sub>, AlCl<sub>3</sub> and a crown ether (18-crown-6 and dibenzo18-crown-6) in MeCN have led to the isolation of four new lanthanoid halide crown ether complexes, [PrCl(μ-Cl)(18-crown-6)]<sub>2</sub>[AlCl<sub>4</sub>]<sub>2</sub>·2MeCN (<strong>1</strong>), [YbCl<sub>2</sub>(18-crown-6)][AlCl<sub>4</sub>]·MeCN (<strong>2</strong>), and [LnCl(μ-Cl)(dibenzo18-crown-6)}<sub>2</sub>][AlCl<sub>4</sub>]<sub>2</sub>·6.5MeCN (Ln = La, <strong>3</strong>, Pr, <strong>4</strong>). <strong>1</strong> was also obtained by unexpected halide transfer on addition of 18-crown-6 (18C6) to MeCN solutions of [Pr(MeCN)<sub>9</sub>][AlCl<sub>4</sub>]<sub>3</sub>. Complexes <strong>1</strong>, <strong>3</strong> and <strong>4</strong> have dinuclear chloride-bridged nine-coordinate cations, and <strong>2</strong> has an eight coordinate mononuclear cation.</div></div>\",\"PeriodicalId\":20278,\"journal\":{\"name\":\"Polyhedron\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.4000,\"publicationDate\":\"2024-10-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Polyhedron\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0277538724004467\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polyhedron","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0277538724004467","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Reactions between LnCl3, AlCl3 and a crown ether (18-crown-6 and dibenzo18-crown-6) in MeCN have led to the isolation of four new lanthanoid halide crown ether complexes, [PrCl(μ-Cl)(18-crown-6)]2[AlCl4]2·2MeCN (1), [YbCl2(18-crown-6)][AlCl4]·MeCN (2), and [LnCl(μ-Cl)(dibenzo18-crown-6)}2][AlCl4]2·6.5MeCN (Ln = La, 3, Pr, 4). 1 was also obtained by unexpected halide transfer on addition of 18-crown-6 (18C6) to MeCN solutions of [Pr(MeCN)9][AlCl4]3. Complexes 1, 3 and 4 have dinuclear chloride-bridged nine-coordinate cations, and 2 has an eight coordinate mononuclear cation.
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Polyhedron publishes original, fundamental, experimental and theoretical work of the highest quality in all the major areas of inorganic chemistry. This includes synthetic chemistry, coordination chemistry, organometallic chemistry, bioinorganic chemistry, and solid-state and materials chemistry.
Papers should be significant pieces of work, and all new compounds must be appropriately characterized. The inclusion of single-crystal X-ray structural data is strongly encouraged, but papers reporting only the X-ray structure determination of a single compound will usually not be considered. Papers on solid-state or materials chemistry will be expected to have a significant molecular chemistry component (such as the synthesis and characterization of the molecular precursors and/or a systematic study of the use of different precursors or reaction conditions) or demonstrate a cutting-edge application (for example inorganic materials for energy applications). Papers dealing only with stability constants are not considered.
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