Bi3+/Te4+ 共掺杂 Cs2SnCl6 中的白光发射,用于可调节的日常照明和可见光通信

IF 3.5 3区 材料科学 Q1 MATERIALS SCIENCE, CERAMICS Journal of the American Ceramic Society Pub Date : 2024-09-25 DOI:10.1111/jace.20159
Jianglong Chang, Sai Xu, Anliang Liu, You Li, Bo Liu, Baojiu Chen
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引用次数: 0

摘要

掺杂 ns2 离子的无铅过氧化物由于其自俘获激子 (STE) 所产生的广泛发射特性,在各种光电应用中的潜力备受关注。本文利用 Bi3+/Te4+ 共掺杂 Cs2SnCl6 开发了用于智能照明的高性能白光发光二极管(WLED)。双 STE 发射之间的有效能量转移产生了覆盖全色区域的可调宽带发射。包含冷白光和暖白光照明的可调式 WLED 制作完成。这种多功能性使其能够满足不同场景的照明需求,这对于未来的 WLED 实现健康照明至关重要。此外,卓越的白光发射特性还可应用于可见光通信(VLC)系统,实现 13.3 MHz 的 -3 dB 带宽,并在 10-60 Mbps 的数据速率范围内打开眼图。这项研究成果标志着在构建智能健康照明应用和实现基于无铅包晶的高质量可见光通信光源方面取得了重大进展。
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White light emission in Bi3+/Te4+ co-doped Cs2SnCl6 for adjustable daily lighting and visible light communication

ns2 ions-doped lead-free perovskites have garnered significant attention for their potential in diverse optoelectronic applications, owing to their broad emission characteristics arising from self-trapped excitons (STEs). Herein, high-performance white light-emitting diodes (WLEDs) for intelligent lighting are developed by Bi3+/Te4+co-doped Cs2SnCl6. Effective energy transfer between the dual STE emissions results in tunable broadband emissions covering the full-color region. Adjustable WLEDs containing cold- and warm-white lighting are fabricated. The WLEDs have excellent luminescent performances coupled with adjustable correlated color temperatures of 6417 and 3829 K. This versatility allows them to meet lighting demand for different scenarios, which is essential for future WLEDs to achieve healthy lighting. In addition, the excellent white light emission characteristics can also be applied in the visible light communication (VLC) system, achieving a −3 dB bandwidth of 13.3 MHz and opening eye diagrams in the data rate range of 10–60 Mbps. This work represents a significant advancement toward building intelligent health lighting applications and achieving high-quality light sources for VLC based on lead-free perovskites.

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来源期刊
Journal of the American Ceramic Society
Journal of the American Ceramic Society 工程技术-材料科学:硅酸盐
CiteScore
7.50
自引率
7.70%
发文量
590
审稿时长
2.1 months
期刊介绍: The Journal of the American Ceramic Society contains records of original research that provide insight into or describe the science of ceramic and glass materials and composites based on ceramics and glasses. These papers include reports on discovery, characterization, and analysis of new inorganic, non-metallic materials; synthesis methods; phase relationships; processing approaches; microstructure-property relationships; and functionalities. Of great interest are works that support understanding founded on fundamental principles using experimental, theoretical, or computational methods or combinations of those approaches. All the published papers must be of enduring value and relevant to the science of ceramics and glasses or composites based on those materials. Papers on fundamental ceramic and glass science are welcome including those in the following areas: Enabling materials for grand challenges[...] Materials design, selection, synthesis and processing methods[...] Characterization of compositions, structures, defects, and properties along with new methods [...] Mechanisms, Theory, Modeling, and Simulation[...] JACerS accepts submissions of full-length Articles reporting original research, in-depth Feature Articles, Reviews of the state-of-the-art with compelling analysis, and Rapid Communications which are short papers with sufficient novelty or impact to justify swift publication.
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