与甲苯-d8 和吡啶-d5 兼容的可逆压缩交联聚苯乙烯凝胶，用于测量残余双极耦合和残余化学位移各向异性。

IF 1.9 3区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Magnetic Resonance in Chemistry Pub Date : 2024-11-04 DOI:10.1002/mrc.5494

Franciane G Dos Santos, Daiane S Carvalho, Fernando Hallwass, Armando Navarro-Vázquez

{"title":"与甲苯-d8 和吡啶-d5 兼容的可逆压缩交联聚苯乙烯凝胶，用于测量残余双极耦合和残余化学位移各向异性。","authors":"Franciane G Dos Santos, Daiane S Carvalho, Fernando Hallwass, Armando Navarro-Vázquez","doi":"10.1002/mrc.5494","DOIUrl":null,"url":null,"abstract":"A chemically cross-linked version of polystyrene is presented here that allows the preparation of reversibly mechanically compressible gels as NMR weakly aligning media. The gels can be successfully swollen in aromatic solvents such as toluene-d8 and pyridine-d5, as well as in CDCl3, and provided accurate measurements of 1DCH RDCs and 13C-RCSAs.","PeriodicalId":18142,"journal":{"name":"Magnetic Resonance in Chemistry","volume":null,"pages":null},"PeriodicalIF":1.9000,"publicationDate":"2024-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Reversibly Compressible Cross-Linked Polystyrene Gels, Compatible With Toluene-d8 and Pyridine-d5, for Measurement of Residual Dipolar Couplings and Residual Chemical Shift Anisotropies.\",\"authors\":\"Franciane G Dos Santos, Daiane S Carvalho, Fernando Hallwass, Armando Navarro-Vázquez\",\"doi\":\"10.1002/mrc.5494\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A chemically cross-linked version of polystyrene is presented here that allows the preparation of reversibly mechanically compressible gels as NMR weakly aligning media. The gels can be successfully swollen in aromatic solvents such as toluene-d8 and pyridine-d5, as well as in CDCl3, and provided accurate measurements of 1DCH RDCs and 13C-RCSAs.\",\"PeriodicalId\":18142,\"journal\":{\"name\":\"Magnetic Resonance in Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.9000,\"publicationDate\":\"2024-11-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Magnetic Resonance in Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1002/mrc.5494\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Magnetic Resonance in Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1002/mrc.5494","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

本文介绍了一种化学交联型聚苯乙烯，它可以制备可逆机械压缩凝胶，作为 NMR 弱对准介质。这种凝胶可以在甲苯-d8 和吡啶-d5 等芳香溶剂以及 CDCl3 中成功溶胀，并提供了 1DCH RDC 和 13C-RCSA 的精确测量。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

Reversibly Compressible Cross-Linked Polystyrene Gels, Compatible With Toluene-d₈ and Pyridine-d₅, for Measurement of Residual Dipolar Couplings and Residual Chemical Shift Anisotropies.

A chemically cross-linked version of polystyrene is presented here that allows the preparation of reversibly mechanically compressible gels as NMR weakly aligning media. The gels can be successfully swollen in aromatic solvents such as toluene-d₈ and pyridine-d₅, as well as in CDCl₃, and provided accurate measurements of ¹D_CH RDCs and ¹³C-RCSAs.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Magnetic Resonance in Chemistry 化学-光谱学

CiteScore

4.70

自引率

10.00%

发文量

审稿时长

1 months

期刊介绍： MRC is devoted to the rapid publication of papers which are concerned with the development of magnetic resonance techniques, or in which the application of such techniques plays a pivotal part. Contributions from scientists working in all areas of NMR, ESR and NQR are invited, and papers describing applications in all branches of chemistry, structural biology and materials chemistry are published. The journal is of particular interest not only to scientists working in academic research, but also those working in commercial organisations who need to keep up-to-date with the latest practical applications of magnetic resonance techniques.