基于 UiO 的 MOF 检测和去除水中抗生素策略综述

IF 2.7 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY New Journal of Chemistry Pub Date : 2024-10-24 DOI:10.1039/D4NJ03409K
Vahid Amani, Fataneh Norouzi and Zakyeh Akrami
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引用次数: 0

摘要

抗生素在水中的广泛使用造成了严重的环境污染,带来了潜在的健康风险。因此,有必要开发有效的方法来去除废水中的抗生素。本综述探讨了 UiO(奥斯陆大学)金属有机框架(MOFs)在吸附水中的染料和药物方面的潜力。与传统吸附剂相比,UiO MOFs 具有超高的孔隙率和卓越的稳定性等优异特性,是吸附污染物的理想候选材料。研究表明,UiO MOFs 在去除水中各种浓度的抗生素方面具有卓越的性能。这种高吸附效率归功于其广泛的布鲁纳-艾美特-泰勒(BET)表面积和孔隙率,为污染物提供了大量的结合位点。UiO MOFs 与抗生素之间的吸附亲和力受静电作用、氢键和 π-π 堆积等各种相互作用的影响。这些相互作用受目标污染物表面电荷和 MOF 表面 zeta 电位的影响。此外,本综述还讨论了抗生素的检测机制,包括荧光淬灭、光催化降解、吸附、传感和其他方法。总之,本综述强调了 UiO MOFs 作为高效吸附剂去除水中抗生素的巨大潜力,为环境净化提供了可行的解决方案。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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A review of UiO-based MOF detection and removal strategies for antibiotics in water

The widespread use of antibiotics in water has resulted in significant environmental contamination, posing potential health risks. This necessitates the development of efficient methods for their removal from wastewater. This review explores the potential of UiO (Universitetet i Oslo) metal–organic frameworks (MOFs) for the adsorption of dyes and pharmaceuticals from water. UiO MOFs possess exceptional characteristics, including ultra-high porosity and remarkable stability, making them ideal candidates for pollutant adsorption compared to traditional adsorbents. Studies have demonstrated the exceptional performance of UiO MOFs in removing antibiotics from water at various concentrations. This high adsorption efficiency is attributed to their extensive Brunauer–Emmett–Teller (BET) surface area and pore volume, offering numerous binding sites for pollutants. The adsorption affinity between UiO MOFs and antibiotics is governed by various interactions, such as electrostatic interactions, hydrogen bonding, and π–π stacking. These interactions are influenced by the surface charge of the target pollutant and the zeta potential of the MOF surface. Furthermore, the detection mechanisms for antibiotics including, fluorescence quenching, photocatalytic degradation, adsorption, sensing, and other methods, are discussed in this review. Overall, this review emphasizes the promising potential of UiO MOFs as efficient adsorbents for removing antibiotics from water, offering a viable solution for environmental cleanup.

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来源期刊
New Journal of Chemistry
New Journal of Chemistry 化学-化学综合
CiteScore
5.30
自引率
6.10%
发文量
1832
审稿时长
2 months
期刊介绍: A journal for new directions in chemistry
期刊最新文献
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