基于双(N-亚烷基苯并噻唑)二溴化物和三乙胺反应的新型大型双层环烷的合成及其结构特征

IF 1.8 3区 化学 Q3 CHEMISTRY, ORGANIC Synthetic Communications Pub Date : 2024-10-18 DOI:10.1080/00397911.2024.2415435
Zhen-zhong Wei , Xing-bao Chi
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引用次数: 0

摘要

以双(N-亚烷基苯并噻唑)二溴化盐为重要合成中间体,通过自由基偶联反应成功合成了一种新型的大型双层环烷。根据核磁共振数据和 X 射线结构分析,分别阐明了二层环烷和合成中间体的结构。双层环烷由两种不同的几何结构组成,内含两个反双环内酰胺酰胺环,外含两个二硫键桥,结构独特新颖。此外,还通过紫外可见光和氧化还原电位研究了它们的物理性质。
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Synthesis and structural characterization of a novel large type double-layered cyclophanes based on the reaction of bis(N-alkylene benzothiazolium) dibromide and triethylamine
The synthesis of a novel large type double-layered cyclophanes has been successfully accomplished by free radical coupling reaction with the bis(N-alkylene benzothiazolium) dibromide salts as their important synthetic intermediates. The structures of the two-layered cyclophanes and the synthetic intermediates have been elucidated based on the NMR data and X-ray structural analysis, respectively. The two-layered cyclophanes consist of two different geometries, anti-two cyclic lactam amide rings inside and two bridges of disulfide bonds outside, which are unique and novel structures. Their physical properties were investigated by UV–Vis and redox potential, too.
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来源期刊
Synthetic Communications
Synthetic Communications 化学-有机化学
CiteScore
4.40
自引率
4.80%
发文量
156
审稿时长
4.3 months
期刊介绍: Synthetic Communications presents communications describing new methods, reagents, and other synthetic work pertaining to organic chemistry with sufficient experimental detail to permit reported reactions to be repeated by a chemist reasonably skilled in the art. In addition, the Journal features short, focused review articles discussing topics within its remit of synthetic organic chemistry.
期刊最新文献
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