Xinyi Wen, Huishan Li, Zhijie Ju, Renren Deng, David Parker
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Mechanism of Action and Evaluation of Ratiometric Probes for Uric Acid Using Lanthanide Complexes with Tetraazatriphenylene Sensitisers
A series of new ligands has been prepared that incorporate electron-poor aromatic moieties (dpqMe2 and dpqPh2 chromophores) into tetraazacyclododecane or triazacyclononane based complex structures, and the time-dependent photophysical properties of their Eu(III) and Tb (III) complexes evaluated for the selective and rapid ratiometric analysis of urate in diluted serum solution, together with detailed mechanistic studies probing the nature of the intermediate exciplex and the excited state dynamics using transient absorption spectroscopy.
期刊介绍：
Chemical Science is a journal that encompasses various disciplines within the chemical sciences. Its scope includes publishing ground-breaking research with significant implications for its respective field, as well as appealing to a wider audience in related areas. To be considered for publication, articles must showcase innovative and original advances in their field of study and be presented in a manner that is understandable to scientists from diverse backgrounds. However, the journal generally does not publish highly specialized research.
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