{"title":"成对电催化使苯乙烯与烷基自由基发生氧化偶联。","authors":"Dong Li, Ling Zhang, Daixi Li, Peng Yu, Tao Shen","doi":"10.1039/d4ob01605j","DOIUrl":null,"url":null,"abstract":"<p><p>A paired electrocatalysis strategy for intermolecular oxidative cross-dehydrocoupling between styrenes and ethers or <i>p</i>-methylphenol derivatives using ketone as a mild oxidant is described. This approach enables the generation of Csp<sup>3</sup> carbon-centered radicals through anodic oxidation, followed by reductive coupling of ketones at the cathode, ultimately yielding valuable oxidative alkylation products.</p>","PeriodicalId":96,"journal":{"name":"Organic & Biomolecular Chemistry","volume":" ","pages":""},"PeriodicalIF":2.9000,"publicationDate":"2024-11-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Paired electrocatalysis enabled oxidative coupling of styrenes with alkyl radicals.\",\"authors\":\"Dong Li, Ling Zhang, Daixi Li, Peng Yu, Tao Shen\",\"doi\":\"10.1039/d4ob01605j\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>A paired electrocatalysis strategy for intermolecular oxidative cross-dehydrocoupling between styrenes and ethers or <i>p</i>-methylphenol derivatives using ketone as a mild oxidant is described. This approach enables the generation of Csp<sup>3</sup> carbon-centered radicals through anodic oxidation, followed by reductive coupling of ketones at the cathode, ultimately yielding valuable oxidative alkylation products.</p>\",\"PeriodicalId\":96,\"journal\":{\"name\":\"Organic & Biomolecular Chemistry\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":2.9000,\"publicationDate\":\"2024-11-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Organic & Biomolecular Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1039/d4ob01605j\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, ORGANIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Organic & Biomolecular Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d4ob01605j","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
Paired electrocatalysis enabled oxidative coupling of styrenes with alkyl radicals.
A paired electrocatalysis strategy for intermolecular oxidative cross-dehydrocoupling between styrenes and ethers or p-methylphenol derivatives using ketone as a mild oxidant is described. This approach enables the generation of Csp3 carbon-centered radicals through anodic oxidation, followed by reductive coupling of ketones at the cathode, ultimately yielding valuable oxidative alkylation products.
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