Xin He , Kun Xie , Weijia Cao , Xiangguo Lu , Xiaoyan Wang , Bin Huang , Nan Zhang , Dandan Cui , Xujie Hong , Yuqing Wang , Xiaoqin Zhang
{"title":"二氧化碳辅助表面活性剂/聚合物淹没对提高石油采收率的影响及其机理","authors":"Xin He , Kun Xie , Weijia Cao , Xiangguo Lu , Xiaoyan Wang , Bin Huang , Nan Zhang , Dandan Cui , Xujie Hong , Yuqing Wang , Xiaoqin Zhang","doi":"10.1016/j.geoen.2024.213473","DOIUrl":null,"url":null,"abstract":"<div><div>D oilfield is a typical heavy oil reservoir affected by bottom water and has the characteristics of high porosity, high permeability, and strong heterogeneity. However, water flooding leaves oil behind due to unfavorable mobility ratios and capillary forces. The layer (well section) with poor or no liquid entry ability originally has been improved in the process of surfactant/polymer flood. However, fluid entry distribution interlayers were not improved obviously in the middle and late stages. To further improve the recovery efficiency of surfactant/polymer flooding on bottom water reservoirs, the CO<sub>2</sub>-assisted surfactant/polymer flooding development method had been proposed. The optimal composition of the surfactant/polymer system was selected by evaluating the oil-water interfacial tension and viscosity. Three-dimensional cores with bottom water were used in CO<sub>2</sub>-assisted surfactant/polymer flooding experiments to improve oil recovery. On this foundation, the screening of oil displacement agents, optimization of oil production well location, and injection pressure were carried out. Based on the comprehensive analysis of the produced liquid, the CO<sub>2</sub> assisted surfactant/polymer flooding to enhanced oil recovery mechanism was analyzed. The results showed that the surfactant named BS had a low oil-water interfacial tension of 3.79 × 10<sup>-</sup><sup>3</sup> mN/m. In addition, salinity decreases the viscosity of the surfactant/polymer solution. It was found that conducting CO<sub>2</sub> huff and puff after chemical flooding can improve oil recovery. Among the four chemical agents, CO<sub>2</sub>-assisted the anionic nonionic surfactant and the salt-resistant polymer system flooding had the highest recovery. Moreover, the location of the oil production well, that is, the distance between it and the bottom water layer, has an impact on the recovery. During the experiment, 2.5 cm was the farthest distance between the oil production well and the bottom water layer, at which point the recovery was highest at 70.9%, and the bottom water breakthrough rate was 2.4%. These results provide theoretical and technical support for the development of CO<sub>2</sub>-assisted surfactant/polymer flooding and its application in wells.</div></div>","PeriodicalId":100578,"journal":{"name":"Geoenergy Science and Engineering","volume":"244 ","pages":"Article 213473"},"PeriodicalIF":0.0000,"publicationDate":"2024-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Effect of CO2-assisted surfactant/polymer flooding on enhanced oil recovery and its mechanism\",\"authors\":\"Xin He , Kun Xie , Weijia Cao , Xiangguo Lu , Xiaoyan Wang , Bin Huang , Nan Zhang , Dandan Cui , Xujie Hong , Yuqing Wang , Xiaoqin Zhang\",\"doi\":\"10.1016/j.geoen.2024.213473\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>D oilfield is a typical heavy oil reservoir affected by bottom water and has the characteristics of high porosity, high permeability, and strong heterogeneity. However, water flooding leaves oil behind due to unfavorable mobility ratios and capillary forces. The layer (well section) with poor or no liquid entry ability originally has been improved in the process of surfactant/polymer flood. However, fluid entry distribution interlayers were not improved obviously in the middle and late stages. To further improve the recovery efficiency of surfactant/polymer flooding on bottom water reservoirs, the CO<sub>2</sub>-assisted surfactant/polymer flooding development method had been proposed. The optimal composition of the surfactant/polymer system was selected by evaluating the oil-water interfacial tension and viscosity. Three-dimensional cores with bottom water were used in CO<sub>2</sub>-assisted surfactant/polymer flooding experiments to improve oil recovery. On this foundation, the screening of oil displacement agents, optimization of oil production well location, and injection pressure were carried out. Based on the comprehensive analysis of the produced liquid, the CO<sub>2</sub> assisted surfactant/polymer flooding to enhanced oil recovery mechanism was analyzed. The results showed that the surfactant named BS had a low oil-water interfacial tension of 3.79 × 10<sup>-</sup><sup>3</sup> mN/m. In addition, salinity decreases the viscosity of the surfactant/polymer solution. It was found that conducting CO<sub>2</sub> huff and puff after chemical flooding can improve oil recovery. Among the four chemical agents, CO<sub>2</sub>-assisted the anionic nonionic surfactant and the salt-resistant polymer system flooding had the highest recovery. Moreover, the location of the oil production well, that is, the distance between it and the bottom water layer, has an impact on the recovery. During the experiment, 2.5 cm was the farthest distance between the oil production well and the bottom water layer, at which point the recovery was highest at 70.9%, and the bottom water breakthrough rate was 2.4%. These results provide theoretical and technical support for the development of CO<sub>2</sub>-assisted surfactant/polymer flooding and its application in wells.</div></div>\",\"PeriodicalId\":100578,\"journal\":{\"name\":\"Geoenergy Science and Engineering\",\"volume\":\"244 \",\"pages\":\"Article 213473\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-11-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Geoenergy Science and Engineering\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2949891024008431\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"0\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Geoenergy Science and Engineering","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2949891024008431","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"0","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
引用次数: 0
摘要
D 油田是一个典型的受底水影响的重油储层,具有高孔隙度、高渗透率和强异质性的特点。然而,由于流动比率和毛细管力的不利影响,水淹会留下石油。在表面活性剂/聚合物水淹过程中,原本液体进入能力差或无液体进入能力的层(井段)得到了改善。但在中后期,液体进入分布夹层的情况并没有得到明显改善。为了进一步提高表面活性剂/聚合物淹没底层储层的回收效率,提出了二氧化碳辅助表面活性剂/聚合物淹没开发方法。通过评估油水界面张力和粘度,选择了最佳的表面活性剂/聚合物体系组成。在二氧化碳辅助表面活性剂/聚合物淹没实验中使用了含有底水的三维岩心,以提高石油采收率。在此基础上,进行了石油置换剂的筛选、采油井位置和注入压力的优化。在对产出液进行综合分析的基础上,分析了二氧化碳辅助表面活性剂/聚合物淹没提高石油采收率的机理。结果表明,名为 BS 的表面活性剂具有较低的油水界面张力,为 3.79 × 10-3 mN/m。此外,盐度会降低表面活性剂/聚合物溶液的粘度。研究发现,在化学淹没后进行 CO2 吹胀可以提高石油采收率。在四种化学剂中,二氧化碳辅助阴离子非离子表面活性剂和耐盐聚合物体系的淹没采收率最高。此外,采油井的位置(即与底层水的距离)对采收率也有影响。在实验中,2.5 厘米是采油井与底层水之间的最远距离,此时采收率最高,为 70.9%,底层水突破率为 2.4%。这些结果为开发二氧化碳辅助表面活性剂/聚合物水淹法及其在油井中的应用提供了理论和技术支持。
Effect of CO2-assisted surfactant/polymer flooding on enhanced oil recovery and its mechanism
D oilfield is a typical heavy oil reservoir affected by bottom water and has the characteristics of high porosity, high permeability, and strong heterogeneity. However, water flooding leaves oil behind due to unfavorable mobility ratios and capillary forces. The layer (well section) with poor or no liquid entry ability originally has been improved in the process of surfactant/polymer flood. However, fluid entry distribution interlayers were not improved obviously in the middle and late stages. To further improve the recovery efficiency of surfactant/polymer flooding on bottom water reservoirs, the CO2-assisted surfactant/polymer flooding development method had been proposed. The optimal composition of the surfactant/polymer system was selected by evaluating the oil-water interfacial tension and viscosity. Three-dimensional cores with bottom water were used in CO2-assisted surfactant/polymer flooding experiments to improve oil recovery. On this foundation, the screening of oil displacement agents, optimization of oil production well location, and injection pressure were carried out. Based on the comprehensive analysis of the produced liquid, the CO2 assisted surfactant/polymer flooding to enhanced oil recovery mechanism was analyzed. The results showed that the surfactant named BS had a low oil-water interfacial tension of 3.79 × 10-3 mN/m. In addition, salinity decreases the viscosity of the surfactant/polymer solution. It was found that conducting CO2 huff and puff after chemical flooding can improve oil recovery. Among the four chemical agents, CO2-assisted the anionic nonionic surfactant and the salt-resistant polymer system flooding had the highest recovery. Moreover, the location of the oil production well, that is, the distance between it and the bottom water layer, has an impact on the recovery. During the experiment, 2.5 cm was the farthest distance between the oil production well and the bottom water layer, at which point the recovery was highest at 70.9%, and the bottom water breakthrough rate was 2.4%. These results provide theoretical and technical support for the development of CO2-assisted surfactant/polymer flooding and its application in wells.