N. G. Hobosyan, K. V. Balyan, H. R. Pogosyan, L. A. Movsisyan, V. S. Hovsepyan, H. B. Sargsyan
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Iodination of Phenylacetylene and Some Transformations of the Resulting Iodo Derivatives
An efficient procedure has been proposed for the reaction of molecular iodine with phenylacetylene in the presence of cadmium(II) acetate in DMSO at room temperature, and the reactant ratio has been optimized for the iodination process. Mercuration–demercuration of iodoethynylbenzene with molecular iodine and oxidative homocoupling in the presence of dilithium tetrachlorocuprate have been performed.
期刊介绍:
Russian Journal of Organic Chemistry is an international peer reviewed journal that covers all aspects of modern organic chemistry including organic synthesis, theoretical organic chemistry, structure and mechanism, and the application of organometallic compounds in organic synthesis.