E. E. Bardina, E. V. Makotchenko, K. P. Birin, E. S. Shremzer, P. A. Abramov, Yu. G. Gorbunova, A. L. Gushchin
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Synthesis and Structure of Gold(III) Compounds with i-Pr- and t-Bu-Substituted Tetraarylporphyrins
Gold(III) compounds with tetrakis(4-tert-butylphenyl)porphyrin, [Au(TTBPP)][AuCl4] (I), and with tetrakis(4-isopropylphenyl)porphyrin, [Au(TIPPP)][AuCl4] (II), were synthesized for the first time. The obtained compounds were characterized by elemental analysis, 1H NMR spectroscopy, cyclic voltammetry, and X-ray diffraction analysis of solvated complexes (CCDC no. 2333206 (Ia) and 2333207 (IIa)). Study of the structures of the obtained gold(III) complexes confirmed their specific character consisting in the formation of additional Au⋯Au and Au⋯Cl contacts between neighboring complexes giving weak intermolecular bonds.
期刊介绍：
Russian Journal of Coordination Chemistry is a journal that publishes reviews, original papers, and short communications on all aspects of theoretical and experimental coordination chemistry. Modern coordination chemistry is an interdisciplinary science that makes a bridge between inorganic, organic, physical, analytical, and biological chemistry.
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