具有优异机械性能的短黄麻纤维增强型二氧化硅气凝胶

IF 3.5 3区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Journal of Materials Science Pub Date : 2024-10-30 DOI:10.1007/s10853-024-10363-7
Long Feng, Ming Cai, Yu Fu, Qihua Ma, Baozhong Sun, Geoffrey I. N. Waterhouse
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引用次数: 0

摘要

气凝胶具有高孔隙率、高比表面积、低密度和低导热性等特点,因此备受关注。然而,高成本、复杂的制造工艺和较差的机械性能阻碍了它们在工业领域的应用。在此,我们研究了用短黄麻(Corchorus olitorius)纤维增强硅基气凝胶的效果。我们制备了含有商用二氧化硅溶胶、水、聚乙烯醇(PVA)、聚乙二醇(PEG)和黄麻纤维的凝胶,然后冷冻干燥 36 小时,得到不同黄麻纤维含量的 SiO2/PVA/PEG-Jute 气凝胶。纤维含量为 3 wt.% 的气凝胶具有优异的隔热性能(导热系数为 0.05355 W/m K),线性伸长率为 80%,抗压强度为 1.1 MPa(比不含黄麻纤维的气凝胶高 8 倍)。因此,添加低成本的黄麻纤维既能保持二氧化硅气凝胶理想的隔热性能,又能显著改善其机械性能(气凝胶的柔韧性、压缩性能和抗收缩性),以适应不同的最终用途。
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Short jute fiber-reinforced silica aerogel with excellent mechanical properties

Aerogels attract a lot of attention due to their high porosity, high specific surface area, low density, and low thermal conductivity. However, high cost, complex manufacturing process, and poor mechanical properties hinder their application in the industrial sector. Herein, we examined the effect of strengthening silica-based aerogels with short jute (Corchorus olitorius) fibers. Gels containing a commercial silica sol, water, polyvinyl alcohol (PVA), polyethylene glycol (PEG) and jute fibers were prepared, then freeze-dried for 36 h to yield SiO2/PVA/PEG-Jute aerogels with different jute fiber contents. The aerogel prepared with a fiber content of 3 wt.% possessed excellent thermal insulation properties (thermal conductivity of 0.05355 W/m K), a linear elongation of 80%, and a compressive strength of 1.1 MPa (8 times higher than the aerogel prepared without jute fibers). The addition of low-cost jute fibers thus maintains the desirable thermal insulation properties of SiO2-based aerogels whilst significantly improving their mechanical properties (aerogel flexibility, compression performance and shrinkage resistance) for different end uses.

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来源期刊
Journal of Materials Science
Journal of Materials Science 工程技术-材料科学:综合
CiteScore
7.90
自引率
4.40%
发文量
1297
审稿时长
2.4 months
期刊介绍: The Journal of Materials Science publishes reviews, full-length papers, and short Communications recording original research results on, or techniques for studying the relationship between structure, properties, and uses of materials. The subjects are seen from international and interdisciplinary perspectives covering areas including metals, ceramics, glasses, polymers, electrical materials, composite materials, fibers, nanostructured materials, nanocomposites, and biological and biomedical materials. The Journal of Materials Science is now firmly established as the leading source of primary communication for scientists investigating the structure and properties of all engineering materials.
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