Xiu Ye, Xiaojie Shi, Xiaojin Miao, Peipei Lu, Meiping Wu
{"title":"孔隙率和介质流动对 LPBF 形成的片状姬多孔结构腐蚀行为的影响研究","authors":"Xiu Ye, Xiaojie Shi, Xiaojin Miao, Peipei Lu, Meiping Wu","doi":"10.1007/s10853-024-10371-7","DOIUrl":null,"url":null,"abstract":"<div><p>In this paper, the corrosion resistance of sheet-gyroid porous structures with different porosities formed by LPBF under static and dynamic conditions was studied, and the mechanism of influence of medium flow on corrosion resistance was explored based on CFD simulation. It was found that the corrosion resistance of porous structures decreased with the increase in porosity in static and dynamic environments, which was mainly related to the increase in forming defects and the decrease in forming quality as the wall thickness of porous structures decreased with the increase in porosity. Under dynamic electrolyte conditions, the wall shear stress generated by the flowing medium on the surface of the porous structures will reduce the stability of the oxide film and increase the corrosion rate. The porous structures exhibited greater corrosion damage in the dynamic electrolyte solution. Based on CFD simulation analysis, it was found that with the increase in porosity, the channel size of porous structures increased, the curvature decreased, the average wall shear stress decreased, and the influence of medium flow on the corrosion rate of porous structure gradually decreased. The relationship model between average wall shear stress and corrosion rate growth rate was established, which provided data support for the subsequent design of porous structures for bone implantation. During the corrosion process, <i>α</i>-Ti and Ti<sub>2</sub>Cu phase form micro-galvanic corrosion, and the preferential dissolution of Ti<sub>2</sub>Cu phase leads to the gradual release of Cu<sup>2+</sup>, which is conducive to improving the antibacterial performance of Ti–Cu implants.</p></div>","PeriodicalId":645,"journal":{"name":"Journal of Materials Science","volume":"59 42","pages":"20028 - 20049"},"PeriodicalIF":3.5000,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Study on the influence of porosity and medium flow on the corrosion behavior of sheet-gyroid porous structures formed by LPBF\",\"authors\":\"Xiu Ye, Xiaojie Shi, Xiaojin Miao, Peipei Lu, Meiping Wu\",\"doi\":\"10.1007/s10853-024-10371-7\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In this paper, the corrosion resistance of sheet-gyroid porous structures with different porosities formed by LPBF under static and dynamic conditions was studied, and the mechanism of influence of medium flow on corrosion resistance was explored based on CFD simulation. It was found that the corrosion resistance of porous structures decreased with the increase in porosity in static and dynamic environments, which was mainly related to the increase in forming defects and the decrease in forming quality as the wall thickness of porous structures decreased with the increase in porosity. Under dynamic electrolyte conditions, the wall shear stress generated by the flowing medium on the surface of the porous structures will reduce the stability of the oxide film and increase the corrosion rate. The porous structures exhibited greater corrosion damage in the dynamic electrolyte solution. Based on CFD simulation analysis, it was found that with the increase in porosity, the channel size of porous structures increased, the curvature decreased, the average wall shear stress decreased, and the influence of medium flow on the corrosion rate of porous structure gradually decreased. The relationship model between average wall shear stress and corrosion rate growth rate was established, which provided data support for the subsequent design of porous structures for bone implantation. During the corrosion process, <i>α</i>-Ti and Ti<sub>2</sub>Cu phase form micro-galvanic corrosion, and the preferential dissolution of Ti<sub>2</sub>Cu phase leads to the gradual release of Cu<sup>2+</sup>, which is conducive to improving the antibacterial performance of Ti–Cu implants.</p></div>\",\"PeriodicalId\":645,\"journal\":{\"name\":\"Journal of Materials Science\",\"volume\":\"59 42\",\"pages\":\"20028 - 20049\"},\"PeriodicalIF\":3.5000,\"publicationDate\":\"2024-11-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Materials Science\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10853-024-10371-7\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Materials Science","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s10853-024-10371-7","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Study on the influence of porosity and medium flow on the corrosion behavior of sheet-gyroid porous structures formed by LPBF
In this paper, the corrosion resistance of sheet-gyroid porous structures with different porosities formed by LPBF under static and dynamic conditions was studied, and the mechanism of influence of medium flow on corrosion resistance was explored based on CFD simulation. It was found that the corrosion resistance of porous structures decreased with the increase in porosity in static and dynamic environments, which was mainly related to the increase in forming defects and the decrease in forming quality as the wall thickness of porous structures decreased with the increase in porosity. Under dynamic electrolyte conditions, the wall shear stress generated by the flowing medium on the surface of the porous structures will reduce the stability of the oxide film and increase the corrosion rate. The porous structures exhibited greater corrosion damage in the dynamic electrolyte solution. Based on CFD simulation analysis, it was found that with the increase in porosity, the channel size of porous structures increased, the curvature decreased, the average wall shear stress decreased, and the influence of medium flow on the corrosion rate of porous structure gradually decreased. The relationship model between average wall shear stress and corrosion rate growth rate was established, which provided data support for the subsequent design of porous structures for bone implantation. During the corrosion process, α-Ti and Ti2Cu phase form micro-galvanic corrosion, and the preferential dissolution of Ti2Cu phase leads to the gradual release of Cu2+, which is conducive to improving the antibacterial performance of Ti–Cu implants.
期刊介绍:
The Journal of Materials Science publishes reviews, full-length papers, and short Communications recording original research results on, or techniques for studying the relationship between structure, properties, and uses of materials. The subjects are seen from international and interdisciplinary perspectives covering areas including metals, ceramics, glasses, polymers, electrical materials, composite materials, fibers, nanostructured materials, nanocomposites, and biological and biomedical materials. The Journal of Materials Science is now firmly established as the leading source of primary communication for scientists investigating the structure and properties of all engineering materials.