孔隙率和介质流动对 LPBF 形成的片状姬多孔结构腐蚀行为的影响研究

IF 3.5 3区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Journal of Materials Science Pub Date : 2024-11-01 DOI:10.1007/s10853-024-10371-7
Xiu Ye, Xiaojie Shi, Xiaojin Miao, Peipei Lu, Meiping Wu
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引用次数: 0

摘要

本文研究了静态和动态条件下 LPBF 形成的不同孔隙率的片状姬状多孔结构的耐腐蚀性能,并基于 CFD 模拟探讨了介质流动对耐腐蚀性能的影响机理。研究发现,在静态和动态环境下,多孔结构的耐腐蚀性随孔隙率的增加而降低,这主要与多孔结构的壁厚随孔隙率的增加而减小,导致成型缺陷增加和成型质量下降有关。在动态电解质条件下,流动介质在多孔结构表面产生的壁面剪应力会降低氧化膜的稳定性,增加腐蚀速率。多孔结构在动态电解质溶液中表现出更大的腐蚀破坏。基于 CFD 模拟分析发现,随着孔隙率的增加,多孔结构的通道尺寸增大,曲率减小,平均壁面剪应力减小,介质流动对多孔结构腐蚀速率的影响逐渐减小。建立了平均壁面剪应力与腐蚀速率增长率的关系模型,为后续骨植入多孔结构的设计提供了数据支持。在腐蚀过程中,α-Ti与Ti2Cu相形成微电蚀作用,Ti2Cu相的优先溶解导致Cu2+逐渐释放,有利于提高Ti-Cu植入体的抗菌性能。
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Study on the influence of porosity and medium flow on the corrosion behavior of sheet-gyroid porous structures formed by LPBF

In this paper, the corrosion resistance of sheet-gyroid porous structures with different porosities formed by LPBF under static and dynamic conditions was studied, and the mechanism of influence of medium flow on corrosion resistance was explored based on CFD simulation. It was found that the corrosion resistance of porous structures decreased with the increase in porosity in static and dynamic environments, which was mainly related to the increase in forming defects and the decrease in forming quality as the wall thickness of porous structures decreased with the increase in porosity. Under dynamic electrolyte conditions, the wall shear stress generated by the flowing medium on the surface of the porous structures will reduce the stability of the oxide film and increase the corrosion rate. The porous structures exhibited greater corrosion damage in the dynamic electrolyte solution. Based on CFD simulation analysis, it was found that with the increase in porosity, the channel size of porous structures increased, the curvature decreased, the average wall shear stress decreased, and the influence of medium flow on the corrosion rate of porous structure gradually decreased. The relationship model between average wall shear stress and corrosion rate growth rate was established, which provided data support for the subsequent design of porous structures for bone implantation. During the corrosion process, α-Ti and Ti2Cu phase form micro-galvanic corrosion, and the preferential dissolution of Ti2Cu phase leads to the gradual release of Cu2+, which is conducive to improving the antibacterial performance of Ti–Cu implants.

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来源期刊
Journal of Materials Science
Journal of Materials Science 工程技术-材料科学:综合
CiteScore
7.90
自引率
4.40%
发文量
1297
审稿时长
2.4 months
期刊介绍: The Journal of Materials Science publishes reviews, full-length papers, and short Communications recording original research results on, or techniques for studying the relationship between structure, properties, and uses of materials. The subjects are seen from international and interdisciplinary perspectives covering areas including metals, ceramics, glasses, polymers, electrical materials, composite materials, fibers, nanostructured materials, nanocomposites, and biological and biomedical materials. The Journal of Materials Science is now firmly established as the leading source of primary communication for scientists investigating the structure and properties of all engineering materials.
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