O. P. Grigorieva, T. B. Shatalova, P. S. Berdonosov, D. O. Charkin, A. A. Gippius, A. V. Tkachev, E. A. Kravchenko, V. A. Dolgikh, K. A. Lyssenko
{"title":"碘酸钐，Sm(IO3)3-HIO3：合成与表征","authors":"O. P. Grigorieva, T. B. Shatalova, P. S. Berdonosov, D. O. Charkin, A. A. Gippius, A. V. Tkachev, E. A. Kravchenko, V. A. Dolgikh, K. A. Lyssenko","doi":"10.1134/S0022476624100068","DOIUrl":null,"url":null,"abstract":"<p>Samarium hydrogen iodate Sm(IO<sub>3</sub>)<sub>3</sub>·HIO<sub>3</sub> was successfully synthesized by the unconventional low-temperature solution-melt method, its structure was determined by X-ray diffraction analysis of single crystals. This compound crystallizes in the monoclinic space group <i>P</i>2<sub>1</sub>/<i>c</i> with lattice parameters: <i>a</i> = 10.4637(6) Å, <i>b</i> = 7.4629(5) Å, <i>c</i> = 14.0174(13) Å, β = 110.53(0), <i>Z</i> = 6. In the studied structure, samarium atoms are surrounded by 8 oxygen atoms in a polyhedron in the form of a distorted square antiprism. The iodate groups are linked through common oxygen atoms of the SmO<sub>8</sub> antiprism into a three-dimensional framework. The compound was characterized by X-ray diffraction, IR and NQR spectroscopy and EDX analysis.</p>","PeriodicalId":668,"journal":{"name":"Journal of Structural Chemistry","volume":"65 10","pages":"1942 - 1949"},"PeriodicalIF":1.2000,"publicationDate":"2024-11-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Samarium Hydrogen Iodate, Sm(IO3)3·HIO3: Synthesis and Characterization\",\"authors\":\"O. P. Grigorieva, T. B. Shatalova, P. S. Berdonosov, D. O. Charkin, A. A. Gippius, A. V. Tkachev, E. A. Kravchenko, V. A. Dolgikh, K. A. Lyssenko\",\"doi\":\"10.1134/S0022476624100068\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Samarium hydrogen iodate Sm(IO<sub>3</sub>)<sub>3</sub>·HIO<sub>3</sub> was successfully synthesized by the unconventional low-temperature solution-melt method, its structure was determined by X-ray diffraction analysis of single crystals. This compound crystallizes in the monoclinic space group <i>P</i>2<sub>1</sub>/<i>c</i> with lattice parameters: <i>a</i> = 10.4637(6) Å, <i>b</i> = 7.4629(5) Å, <i>c</i> = 14.0174(13) Å, β = 110.53(0), <i>Z</i> = 6. In the studied structure, samarium atoms are surrounded by 8 oxygen atoms in a polyhedron in the form of a distorted square antiprism. The iodate groups are linked through common oxygen atoms of the SmO<sub>8</sub> antiprism into a three-dimensional framework. The compound was characterized by X-ray diffraction, IR and NQR spectroscopy and EDX analysis.</p>\",\"PeriodicalId\":668,\"journal\":{\"name\":\"Journal of Structural Chemistry\",\"volume\":\"65 10\",\"pages\":\"1942 - 1949\"},\"PeriodicalIF\":1.2000,\"publicationDate\":\"2024-11-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Structural Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0022476624100068\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Structural Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0022476624100068","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Samarium Hydrogen Iodate, Sm(IO3)3·HIO3: Synthesis and Characterization
Samarium hydrogen iodate Sm(IO3)3·HIO3 was successfully synthesized by the unconventional low-temperature solution-melt method, its structure was determined by X-ray diffraction analysis of single crystals. This compound crystallizes in the monoclinic space group P21/c with lattice parameters: a = 10.4637(6) Å, b = 7.4629(5) Å, c = 14.0174(13) Å, β = 110.53(0), Z = 6. In the studied structure, samarium atoms are surrounded by 8 oxygen atoms in a polyhedron in the form of a distorted square antiprism. The iodate groups are linked through common oxygen atoms of the SmO8 antiprism into a three-dimensional framework. The compound was characterized by X-ray diffraction, IR and NQR spectroscopy and EDX analysis.
期刊介绍：
Journal is an interdisciplinary publication covering all aspects of structural chemistry, including the theory of molecular structure and chemical bond; the use of physical methods to study the electronic and spatial structure of chemical species; structural features of liquids, solutions, surfaces, supramolecular systems, nano- and solid materials; and the crystal structure of solids.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
