{"title":"挥发性 Co(II)、Ni(II)、Cu(II)、Pd(II) 和 Pt(II) 与 β-酮亚胺配合物系列中的分子间相互作用和异构性","authors":"I. A. Baidina, N. V. Pervukhina, S. A. Gromilov","doi":"10.1134/S0022476624100081","DOIUrl":null,"url":null,"abstract":"<p>We report a comparative crystal chemical analysis of volatile homoligand complexes of Co(II), Ni(II), Cu(II), Pd(II), and Pt(II) with β-ketoimines utilized as precursors in the preparation of oxide and metal film coatings for various purposes using chemical vapor deposition. The crystal structures and intermolecular interactions of β-ketoiminates with the general formula <i>M</i>(L)<sub>2</sub> (L = (<i>R</i>1-C(O)CH-C(N-<i>R</i>3)-<i>R</i>2)<sub>2</sub>; <i>R</i>1, <i>R</i>2 = CH<sub>3</sub>, CF<sub>3</sub>, C(CH<sub>3</sub>)<sub>3</sub>, C(OCH<sub>3</sub>)(CH<sub>2</sub>)<sub>2</sub> in various combinations; <i>R</i>3 = H, CH<sub>3</sub>) are studied.</p>","PeriodicalId":668,"journal":{"name":"Journal of Structural Chemistry","volume":"65 10","pages":"1961 - 1981"},"PeriodicalIF":1.2000,"publicationDate":"2024-11-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Intermolecular Interactions and Isostructurality in the Series of Volatile Co(II), Ni(II), Cu(II), Pd(II), and Pt(II) Complexes with β-Ketoimines\",\"authors\":\"I. A. Baidina, N. V. Pervukhina, S. A. Gromilov\",\"doi\":\"10.1134/S0022476624100081\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>We report a comparative crystal chemical analysis of volatile homoligand complexes of Co(II), Ni(II), Cu(II), Pd(II), and Pt(II) with β-ketoimines utilized as precursors in the preparation of oxide and metal film coatings for various purposes using chemical vapor deposition. The crystal structures and intermolecular interactions of β-ketoiminates with the general formula <i>M</i>(L)<sub>2</sub> (L = (<i>R</i>1-C(O)CH-C(N-<i>R</i>3)-<i>R</i>2)<sub>2</sub>; <i>R</i>1, <i>R</i>2 = CH<sub>3</sub>, CF<sub>3</sub>, C(CH<sub>3</sub>)<sub>3</sub>, C(OCH<sub>3</sub>)(CH<sub>2</sub>)<sub>2</sub> in various combinations; <i>R</i>3 = H, CH<sub>3</sub>) are studied.</p>\",\"PeriodicalId\":668,\"journal\":{\"name\":\"Journal of Structural Chemistry\",\"volume\":\"65 10\",\"pages\":\"1961 - 1981\"},\"PeriodicalIF\":1.2000,\"publicationDate\":\"2024-11-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Structural Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0022476624100081\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Structural Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0022476624100081","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Intermolecular Interactions and Isostructurality in the Series of Volatile Co(II), Ni(II), Cu(II), Pd(II), and Pt(II) Complexes with β-Ketoimines
We report a comparative crystal chemical analysis of volatile homoligand complexes of Co(II), Ni(II), Cu(II), Pd(II), and Pt(II) with β-ketoimines utilized as precursors in the preparation of oxide and metal film coatings for various purposes using chemical vapor deposition. The crystal structures and intermolecular interactions of β-ketoiminates with the general formula M(L)2 (L = (R1-C(O)CH-C(N-R3)-R2)2; R1, R2 = CH3, CF3, C(CH3)3, C(OCH3)(CH2)2 in various combinations; R3 = H, CH3) are studied.
期刊介绍：
Journal is an interdisciplinary publication covering all aspects of structural chemistry, including the theory of molecular structure and chemical bond; the use of physical methods to study the electronic and spatial structure of chemical species; structural features of liquids, solutions, surfaces, supramolecular systems, nano- and solid materials; and the crystal structure of solids.
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