用于瞬态生物可降解电子设备的长效、柔性和完全生物可吸收的 AZ31 钨电池

IF 10.7 2区 材料科学 Q1 CHEMISTRY, PHYSICAL Journal of Materials Chemistry A Pub Date : 2024-11-12 DOI:10.1039/d4ta06222a
Gwan-Jin Ko, Tae-Min Jang, Daiha Shin, Heeseok Kang, Seung Min Yang, Sungkeun Han, Rajaram Kaveti, Chan-Hwi Eom, So Jeong Choi, Won Bae Han, Woon-Hong Yeo, Amay J. Bandodkar, Jiung Cho, Suk-Won Hwang
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引用次数: 0

摘要

快速的技术革命产生了各种便捷的工具,而电池的生产和消费尤其导致了包括环境污染在内的各种问题。尽管为解决这些问题所做的努力增加了人们对绿色可溶解电池的兴趣,但由于可供选择的材料有限,电池的短使用寿命仍被认为是一个主要障碍。在此,我们提出了可生物降解的环保型镁合金-钨(AZ31-W)电池的材料和系统设计,这种电池具有长期稳定性和更强的耐腐蚀性。材料和电化学检测证实,AZ31 阳极和 W 阴极具有卓越的电化学耐受性和稳定可靠的电位。将单个电池组装到市售的袋装电池中,可获得 ∼430 mA h g-1 的高容量,适用于高能量应用。将海藻酸软弹性电解质与电极整合在一起,可实现完全生态可吸收的固态电池,在各种物理变形情况下都能保持性能。研究结果表明,在商业电池对环境或人体构成风险的地方,这种电池具有生物医学和生态友好型应用的潜力。
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Long-lasting, flexible and fully bioresorbable AZ31–tungsten batteries for transient, biodegradable electronics
Rapid technological revolution produces a wide range of convenient tools, while, in particular, the production and consumption of batteries lead to various issues including environmental pollution. Although efforts to solve such problems increase interest in green and dissolvable batteries, their short service life is still recognized as a major obstacle due to limited options of materials. Here, we propose materials and system designs for eco-friendly and biodegradable magnesium alloy–tungsten (AZ31–W) batteries that offer long-term stability with enhanced corrosion resistance. Materials and electrochemical inspections confirm the superior electrochemical tolerance and stable, reliable potentials of the AZ31 anode and W cathode. The assembly of an individual cell into a commercially available pouch battery yields a high capacity of ∼430 mA h g−1, suitable for high-energy applications. The integration of alginate-based soft, elastic electrolytes with the electrodes enables the achievement of completely eco-resorbable solid-state batteries that maintain performance under diverse physical deformations. The results suggest potential for biomedical and eco-friendly applications where commercial batteries pose risks to the environment or human body.
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来源期刊
Journal of Materials Chemistry A
Journal of Materials Chemistry A CHEMISTRY, PHYSICAL-ENERGY & FUELS
CiteScore
19.50
自引率
5.00%
发文量
1892
审稿时长
1.5 months
期刊介绍: The Journal of Materials Chemistry A, B & C covers a wide range of high-quality studies in the field of materials chemistry, with each section focusing on specific applications of the materials studied. Journal of Materials Chemistry A emphasizes applications in energy and sustainability, including topics such as artificial photosynthesis, batteries, and fuel cells. Journal of Materials Chemistry B focuses on applications in biology and medicine, while Journal of Materials Chemistry C covers applications in optical, magnetic, and electronic devices. Example topic areas within the scope of Journal of Materials Chemistry A include catalysis, green/sustainable materials, sensors, and water treatment, among others.
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