{"title":"非贵金属催化剂在 N-乙基咔唑储氢方面的最新进展","authors":"Hansai Wu, junming Zhang, Zicong Wang, Xianglong Kong, Gaofu Li, Ying Zhao, Piaoping Yang, Zhiliang Liu","doi":"10.1039/d4ta06468b","DOIUrl":null,"url":null,"abstract":"N-ethylcarbazole (NEC) hydrogen storage has garnered significant attention owing to its large-scale safe storage of hydrogen superiority. However, the sluggish hydrogenation kinetics in NEC are extremely dependent on catalysts with superior catalytic activity and high selectivity. Numerous researches have demonstrated noble metal catalysts present the best catalytic performance in NEC hydrogen storage, but their high cost impedes widespread commercial applications. In contrast, non-noble metal catalysts effectively address the high-cost issue associated with noble metal catalysts. Furthermore, by optimizing the structural design of the catalysts and increasing the density of active sites, their catalytic performance can be significantly enhanced. This approach achieves a better balance between cost-effectiveness and catalytic efficiency. Therefore, this review first summarizes the synthetic methods and typical structures of NEC hydrogenation non-noble metal catalysts. Subsequently, the recent advances and catalytic mechanisms regarding non-noble metal catalysts for hydrogenation are discussed in detail. Finally, through in-depth analysis of potential problems and active exploration of future prospects, we can better guide the relevant research and application work in the future to continuously reach new heights.","PeriodicalId":82,"journal":{"name":"Journal of Materials Chemistry A","volume":"51 1","pages":""},"PeriodicalIF":10.7000,"publicationDate":"2024-11-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Recent Advances on Non-noble Metal Catalysts toward N-ethylcarbazole Hydrogen Storage\",\"authors\":\"Hansai Wu, junming Zhang, Zicong Wang, Xianglong Kong, Gaofu Li, Ying Zhao, Piaoping Yang, Zhiliang Liu\",\"doi\":\"10.1039/d4ta06468b\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"N-ethylcarbazole (NEC) hydrogen storage has garnered significant attention owing to its large-scale safe storage of hydrogen superiority. However, the sluggish hydrogenation kinetics in NEC are extremely dependent on catalysts with superior catalytic activity and high selectivity. Numerous researches have demonstrated noble metal catalysts present the best catalytic performance in NEC hydrogen storage, but their high cost impedes widespread commercial applications. In contrast, non-noble metal catalysts effectively address the high-cost issue associated with noble metal catalysts. Furthermore, by optimizing the structural design of the catalysts and increasing the density of active sites, their catalytic performance can be significantly enhanced. This approach achieves a better balance between cost-effectiveness and catalytic efficiency. Therefore, this review first summarizes the synthetic methods and typical structures of NEC hydrogenation non-noble metal catalysts. Subsequently, the recent advances and catalytic mechanisms regarding non-noble metal catalysts for hydrogenation are discussed in detail. Finally, through in-depth analysis of potential problems and active exploration of future prospects, we can better guide the relevant research and application work in the future to continuously reach new heights.\",\"PeriodicalId\":82,\"journal\":{\"name\":\"Journal of Materials Chemistry A\",\"volume\":\"51 1\",\"pages\":\"\"},\"PeriodicalIF\":10.7000,\"publicationDate\":\"2024-11-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Materials Chemistry A\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1039/d4ta06468b\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Materials Chemistry A","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1039/d4ta06468b","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
摘要
N-乙基咔唑(NEC)储氢因其大规模安全储氢的优越性而备受关注。然而,NEC 中缓慢的氢化动力学极其依赖于具有卓越催化活性和高选择性的催化剂。大量研究表明,贵金属催化剂在 NEC 储氢中具有最佳的催化性能,但其高昂的成本阻碍了其广泛的商业应用。相比之下,非贵金属催化剂能有效解决贵金属催化剂的高成本问题。此外,通过优化催化剂的结构设计和增加活性位点密度,可以显著提高催化性能。这种方法在成本效益和催化效率之间实现了更好的平衡。因此,本综述首先总结了 NEC 加氢非贵金属催化剂的合成方法和典型结构。随后,详细讨论了非贵金属加氢催化剂的最新研究进展和催化机理。最后,通过对潜在问题的深入分析和对未来前景的积极探索,我们可以更好地指导今后的相关研究和应用工作,不断达到新的高度。
Recent Advances on Non-noble Metal Catalysts toward N-ethylcarbazole Hydrogen Storage
N-ethylcarbazole (NEC) hydrogen storage has garnered significant attention owing to its large-scale safe storage of hydrogen superiority. However, the sluggish hydrogenation kinetics in NEC are extremely dependent on catalysts with superior catalytic activity and high selectivity. Numerous researches have demonstrated noble metal catalysts present the best catalytic performance in NEC hydrogen storage, but their high cost impedes widespread commercial applications. In contrast, non-noble metal catalysts effectively address the high-cost issue associated with noble metal catalysts. Furthermore, by optimizing the structural design of the catalysts and increasing the density of active sites, their catalytic performance can be significantly enhanced. This approach achieves a better balance between cost-effectiveness and catalytic efficiency. Therefore, this review first summarizes the synthetic methods and typical structures of NEC hydrogenation non-noble metal catalysts. Subsequently, the recent advances and catalytic mechanisms regarding non-noble metal catalysts for hydrogenation are discussed in detail. Finally, through in-depth analysis of potential problems and active exploration of future prospects, we can better guide the relevant research and application work in the future to continuously reach new heights.
期刊介绍:
The Journal of Materials Chemistry A, B & C covers a wide range of high-quality studies in the field of materials chemistry, with each section focusing on specific applications of the materials studied. Journal of Materials Chemistry A emphasizes applications in energy and sustainability, including topics such as artificial photosynthesis, batteries, and fuel cells. Journal of Materials Chemistry B focuses on applications in biology and medicine, while Journal of Materials Chemistry C covers applications in optical, magnetic, and electronic devices. Example topic areas within the scope of Journal of Materials Chemistry A include catalysis, green/sustainable materials, sensors, and water treatment, among others.