基于单萜的完全环保型工艺实现了高性能、可在环境中加工的有机太阳能电池

IF 10.7 2区 材料科学 Q1 CHEMISTRY, PHYSICAL Journal of Materials Chemistry A Pub Date : 2024-11-13 DOI:10.1039/d4ta07223e
Hyerin Jeon, Jin-Woo Lee, Kihyun Bae, Tan Ngoc-Lan Phan, Chulhee Lim, Jaeyoung Choi, Cheng Wang, Seungjin Lee, Bumjoon Kim
{"title":"基于单萜的完全环保型工艺实现了高性能、可在环境中加工的有机太阳能电池","authors":"Hyerin Jeon, Jin-Woo Lee, Kihyun Bae, Tan Ngoc-Lan Phan, Chulhee Lim, Jaeyoung Choi, Cheng Wang, Seungjin Lee, Bumjoon Kim","doi":"10.1039/d4ta07223e","DOIUrl":null,"url":null,"abstract":"Conventional processing solvents for organic electronics pose significant health/environmental risks, prompting the search for greener/safer alternatives. Herein, we develop organic solar cells (OSCs), processed from a single terpene solvent, eucalyptol (Eu), with almost no environmental hazards and toxicity. Notably, a record-high power conversion efficiency (PCE) of 15.1% is achieved without any additive, which is particularly significant given the low PCEs (0.1–3.0%) of previous OSCs using a single terpene. First, we design a small-molecule acceptor (MYBO) with optimized side-chains, offering sufficient solubility while maintaining excellent optoelectronic properties. Second, we develop a processing technique which controls the film-formation kinetics to independently tune the aggregation of polymer donor and MYBO. This enables the formation of well-developed MYBO crystallites embedded within interconnected polymer fibrillar structures. And, all the solution processing can be performed in air without using a glove box, thanks to the eco-friendly Eu process. The devices also exhibit excellent air-stability, retaining more than 92% of the initial PCE after 2300 hr in air. This work provides important guidelines for material designs and processing methods to achieve eco-friendly processed, high-performance OSCs.","PeriodicalId":82,"journal":{"name":"Journal of Materials Chemistry A","volume":"80 1","pages":""},"PeriodicalIF":10.7000,"publicationDate":"2024-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"High-Performance, Ambient-Processable Organic Solar Cells Achieved by Single Terpene-Based Entirely Eco-Friendly Process\",\"authors\":\"Hyerin Jeon, Jin-Woo Lee, Kihyun Bae, Tan Ngoc-Lan Phan, Chulhee Lim, Jaeyoung Choi, Cheng Wang, Seungjin Lee, Bumjoon Kim\",\"doi\":\"10.1039/d4ta07223e\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Conventional processing solvents for organic electronics pose significant health/environmental risks, prompting the search for greener/safer alternatives. Herein, we develop organic solar cells (OSCs), processed from a single terpene solvent, eucalyptol (Eu), with almost no environmental hazards and toxicity. Notably, a record-high power conversion efficiency (PCE) of 15.1% is achieved without any additive, which is particularly significant given the low PCEs (0.1–3.0%) of previous OSCs using a single terpene. First, we design a small-molecule acceptor (MYBO) with optimized side-chains, offering sufficient solubility while maintaining excellent optoelectronic properties. Second, we develop a processing technique which controls the film-formation kinetics to independently tune the aggregation of polymer donor and MYBO. This enables the formation of well-developed MYBO crystallites embedded within interconnected polymer fibrillar structures. And, all the solution processing can be performed in air without using a glove box, thanks to the eco-friendly Eu process. The devices also exhibit excellent air-stability, retaining more than 92% of the initial PCE after 2300 hr in air. This work provides important guidelines for material designs and processing methods to achieve eco-friendly processed, high-performance OSCs.\",\"PeriodicalId\":82,\"journal\":{\"name\":\"Journal of Materials Chemistry A\",\"volume\":\"80 1\",\"pages\":\"\"},\"PeriodicalIF\":10.7000,\"publicationDate\":\"2024-11-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Materials Chemistry A\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1039/d4ta07223e\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Materials Chemistry A","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1039/d4ta07223e","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0

摘要

用于有机电子产品的传统加工溶剂对健康和环境构成了巨大的风险,这促使人们寻找更环保、更安全的替代品。在这里,我们开发出了用单一萜烯溶剂桉叶油醇(Eu)加工而成的有机太阳能电池(OSC),几乎没有环境危害和毒性。值得注意的是,在不使用任何添加剂的情况下,我们实现了 15.1% 的创纪录高功率转换效率(PCE),考虑到之前使用单一萜烯的有机太阳能电池的低 PCE(0.1-3.0%),这一点尤为重要。首先,我们设计了一种具有优化侧链的小分子受体(MYBO),在提供足够溶解度的同时保持了出色的光电特性。其次,我们开发了一种控制成膜动力学的加工技术,可独立调节聚合物供体和 MYBO 的聚集。这样就能在相互连接的聚合物纤维结构中形成发达的 MYBO 结晶。此外,由于采用了环保的 Eu 工艺,所有的溶液处理均可在空气中进行,无需使用手套箱。这些器件还表现出卓越的空气稳定性,在空气中放置 2300 小时后,仍能保持 92% 以上的初始 PCE。这项工作为材料设计和加工方法提供了重要指导,以实现环保加工的高性能 OSC。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
High-Performance, Ambient-Processable Organic Solar Cells Achieved by Single Terpene-Based Entirely Eco-Friendly Process
Conventional processing solvents for organic electronics pose significant health/environmental risks, prompting the search for greener/safer alternatives. Herein, we develop organic solar cells (OSCs), processed from a single terpene solvent, eucalyptol (Eu), with almost no environmental hazards and toxicity. Notably, a record-high power conversion efficiency (PCE) of 15.1% is achieved without any additive, which is particularly significant given the low PCEs (0.1–3.0%) of previous OSCs using a single terpene. First, we design a small-molecule acceptor (MYBO) with optimized side-chains, offering sufficient solubility while maintaining excellent optoelectronic properties. Second, we develop a processing technique which controls the film-formation kinetics to independently tune the aggregation of polymer donor and MYBO. This enables the formation of well-developed MYBO crystallites embedded within interconnected polymer fibrillar structures. And, all the solution processing can be performed in air without using a glove box, thanks to the eco-friendly Eu process. The devices also exhibit excellent air-stability, retaining more than 92% of the initial PCE after 2300 hr in air. This work provides important guidelines for material designs and processing methods to achieve eco-friendly processed, high-performance OSCs.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Journal of Materials Chemistry A
Journal of Materials Chemistry A CHEMISTRY, PHYSICAL-ENERGY & FUELS
CiteScore
19.50
自引率
5.00%
发文量
1892
审稿时长
1.5 months
期刊介绍: The Journal of Materials Chemistry A, B & C covers a wide range of high-quality studies in the field of materials chemistry, with each section focusing on specific applications of the materials studied. Journal of Materials Chemistry A emphasizes applications in energy and sustainability, including topics such as artificial photosynthesis, batteries, and fuel cells. Journal of Materials Chemistry B focuses on applications in biology and medicine, while Journal of Materials Chemistry C covers applications in optical, magnetic, and electronic devices. Example topic areas within the scope of Journal of Materials Chemistry A include catalysis, green/sustainable materials, sensors, and water treatment, among others.
期刊最新文献
Manipulating defects simultaneously boosts the crystal stability and the electrochemical reversibility toward long-life aqueous zinc ion batteries Light-induced degradation of methylammonium tin iodide absorber layers High-voltage Symmetric Supercapacitors Developed by Engineering DyFeO3 Electrodes and Aqueous Electrolytes Advancing High Capacity 3D VO2(B) Cathodes for Improved Zinc-ion Battery Performance High-temperature oxidation behavior of transition metal complex concentrated alloys (TM-CCAs): a comprehensive review
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1