用有机硅试剂对不饱和碳氢化合物进行双官能化处理的最新进展。

IF 2.7 3区化学 Q1 CHEMISTRY, ORGANIC Organic & Biomolecular Chemistry Pub Date : 2024-11-07 Epub Date: 2024-10-29 DOI:10.1039/d4ob01471e

Jiawei Mao , Ming Chen , Yao Zhong , Ren-Jie Song

{"title":"用有机硅试剂对不饱和碳氢化合物进行双官能化处理的最新进展。","authors":"Jiawei Mao , Ming Chen , Yao Zhong , Ren-Jie Song","doi":"10.1039/d4ob01471e","DOIUrl":null,"url":null,"abstract":"<div><div>Organosilicon compounds have attracted considerable attention because of their special biological activities. Direct difunctionalization of unsaturated hydrocarbons with organosilicon reagents for the efficient construction of synthetically valuable silicon-functionalized compounds are featured with a high step and atom economy, which could form carbon–silicon/carbon–carbon bonds or carbon–silicon/carbon-hetero bonds in one step. This review summarizes the recent advances on this topic based on different unsaturated hydrocarbons along with typical examples and mechanisms.</div></div>","PeriodicalId":96,"journal":{"name":"Organic & Biomolecular Chemistry","volume":"23 1","pages":"Pages 59-77"},"PeriodicalIF":2.7000,"publicationDate":"2024-11-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Recent developments in difunctionalization of unsaturated hydrocarbons with organosilicon reagents\",\"authors\":\"Jiawei Mao , Ming Chen , Yao Zhong , Ren-Jie Song\",\"doi\":\"10.1039/d4ob01471e\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Organosilicon compounds have attracted considerable attention because of their special biological activities. Direct difunctionalization of unsaturated hydrocarbons with organosilicon reagents for the efficient construction of synthetically valuable silicon-functionalized compounds are featured with a high step and atom economy, which could form carbon–silicon/carbon–carbon bonds or carbon–silicon/carbon-hetero bonds in one step. This review summarizes the recent advances on this topic based on different unsaturated hydrocarbons along with typical examples and mechanisms.</div></div>\",\"PeriodicalId\":96,\"journal\":{\"name\":\"Organic & Biomolecular Chemistry\",\"volume\":\"23 1\",\"pages\":\"Pages 59-77\"},\"PeriodicalIF\":2.7000,\"publicationDate\":\"2024-11-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Organic & Biomolecular Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S1477052024009881\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2024/10/29 0:00:00\",\"PubModel\":\"Epub\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, ORGANIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Organic & Biomolecular Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1477052024009881","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/10/29 0:00:00","PubModel":"Epub","JCR":"Q1","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}

引用次数: 0

摘要

有机硅化合物因其特殊的生物活性而备受关注。用有机硅试剂直接对不饱和碳氢化合物进行双官能化，以高效构建具有合成价值的硅官能化化合物，具有步骤和原子经济性高的特点，可在一个步骤中形成碳-硅/碳-碳键或碳-硅/碳-异键。本综述以不同的不饱和碳氢化合物为基础，总结了这一主题的最新进展以及典型实例和机理。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

摘要图片

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

Recent developments in difunctionalization of unsaturated hydrocarbons with organosilicon reagents

Organosilicon compounds have attracted considerable attention because of their special biological activities. Direct difunctionalization of unsaturated hydrocarbons with organosilicon reagents for the efficient construction of synthetically valuable silicon-functionalized compounds are featured with a high step and atom economy, which could form carbon–silicon/carbon–carbon bonds or carbon–silicon/carbon-hetero bonds in one step. This review summarizes the recent advances on this topic based on different unsaturated hydrocarbons along with typical examples and mechanisms.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Organic & Biomolecular Chemistry 化学-有机化学

CiteScore

5.50

自引率

9.40%

发文量

1056

审稿时长

1.3 months

期刊介绍： Organic & Biomolecular Chemistry is an international journal using integrated research in chemistry-organic chemistry. Founded in 2003 by the Royal Society of Chemistry, the journal is published in Semimonthly issues and has been indexed by SCIE, a leading international database. The journal focuses on the key research and cutting-edge progress in the field of chemistry-organic chemistry, publishes and reports the research results in this field in a timely manner, and is committed to becoming a window and platform for rapid academic exchanges among peers in this field. The journal's impact factor in 2023 is 2.9, and its CiteScore is 5.5.