{"title":"发光配位聚合物：刺激响应凝胶、基于 PMMA 的复合薄膜和紫外线屏蔽","authors":"Bilash Chandra Roy, Vishwakarma Ravikumar Ramlal, Dipmalya Basak, Suvramalya Basak, Saheli Roy, Samrat Ghosh, Tufan Singha Mahapatra","doi":"10.1021/acs.inorgchem.4c04333","DOIUrl":null,"url":null,"abstract":"Lanthanide-based light-emitting coordination polymers (CPs) and CP gels (CPGs) have significance for applications in optical systems, image processing/multiplexing, and optical sensors. In this study, we report two new luminescent CPs (EuL-CP (<b>1</b>) and TbL-CP (<b>2</b>)) and CPGs (EuL-gel (<b>5</b>) and TbL-gel (<b>6</b>)) using lanthanide(III) ions (Ln(III) = Eu(III) and Tb(III)) and 4-(4-carboxyphenyl)-2,2:6,2-terpyridine ligand (<b>L</b>) capable of forming stable thermoreversible gels. Probable structures of EuL-CP (<b>1</b>) and TbL-CP (<b>2</b>) and the formations of EuL-gel (<b>5</b>) and TbL-gel (<b>6</b>) are proposed based on adequate computational studies. The CPGs are stimuli-responsive and could be utilized as invisible security inks for encryption. Further, poly(methyl methacrylate) (PMMA) polymer doped with respective CPs (0.75 wt %) is found to be suitable for forming composite films with UV-shielding properties.","PeriodicalId":40,"journal":{"name":"Inorganic Chemistry","volume":null,"pages":null},"PeriodicalIF":4.3000,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Light-Emitting Coordination Polymers: Stimuli-Responsive Gels, PMMA-Based Composite Films, and UV-Shielding\",\"authors\":\"Bilash Chandra Roy, Vishwakarma Ravikumar Ramlal, Dipmalya Basak, Suvramalya Basak, Saheli Roy, Samrat Ghosh, Tufan Singha Mahapatra\",\"doi\":\"10.1021/acs.inorgchem.4c04333\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Lanthanide-based light-emitting coordination polymers (CPs) and CP gels (CPGs) have significance for applications in optical systems, image processing/multiplexing, and optical sensors. In this study, we report two new luminescent CPs (EuL-CP (<b>1</b>) and TbL-CP (<b>2</b>)) and CPGs (EuL-gel (<b>5</b>) and TbL-gel (<b>6</b>)) using lanthanide(III) ions (Ln(III) = Eu(III) and Tb(III)) and 4-(4-carboxyphenyl)-2,2:6,2-terpyridine ligand (<b>L</b>) capable of forming stable thermoreversible gels. Probable structures of EuL-CP (<b>1</b>) and TbL-CP (<b>2</b>) and the formations of EuL-gel (<b>5</b>) and TbL-gel (<b>6</b>) are proposed based on adequate computational studies. The CPGs are stimuli-responsive and could be utilized as invisible security inks for encryption. Further, poly(methyl methacrylate) (PMMA) polymer doped with respective CPs (0.75 wt %) is found to be suitable for forming composite films with UV-shielding properties.\",\"PeriodicalId\":40,\"journal\":{\"name\":\"Inorganic Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":4.3000,\"publicationDate\":\"2024-11-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Inorganic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1021/acs.inorgchem.4c04333\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1021/acs.inorgchem.4c04333","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Light-Emitting Coordination Polymers: Stimuli-Responsive Gels, PMMA-Based Composite Films, and UV-Shielding
Lanthanide-based light-emitting coordination polymers (CPs) and CP gels (CPGs) have significance for applications in optical systems, image processing/multiplexing, and optical sensors. In this study, we report two new luminescent CPs (EuL-CP (1) and TbL-CP (2)) and CPGs (EuL-gel (5) and TbL-gel (6)) using lanthanide(III) ions (Ln(III) = Eu(III) and Tb(III)) and 4-(4-carboxyphenyl)-2,2:6,2-terpyridine ligand (L) capable of forming stable thermoreversible gels. Probable structures of EuL-CP (1) and TbL-CP (2) and the formations of EuL-gel (5) and TbL-gel (6) are proposed based on adequate computational studies. The CPGs are stimuli-responsive and could be utilized as invisible security inks for encryption. Further, poly(methyl methacrylate) (PMMA) polymer doped with respective CPs (0.75 wt %) is found to be suitable for forming composite films with UV-shielding properties.
期刊介绍：
Inorganic Chemistry publishes fundamental studies in all phases of inorganic chemistry. Coverage includes experimental and theoretical reports on quantitative studies of structure and thermodynamics, kinetics, mechanisms of inorganic reactions, bioinorganic chemistry, and relevant aspects of organometallic chemistry, solid-state phenomena, and chemical bonding theory. Emphasis is placed on the synthesis, structure, thermodynamics, reactivity, spectroscopy, and bonding properties of significant new and known compounds.
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