在水凝胶中进行滑动诱导再水化以恢复润滑和防渗能力

IF 4.8 2区 化学 Q2 CHEMISTRY, PHYSICAL The Journal of Physical Chemistry Letters Pub Date : 2024-11-05 DOI:10.1021/acs.jpclett.4c0238310.1021/acs.jpclett.4c02383
Yunlei Zhang, Carmine Putignano, Changmin Qi, Weiyi Zhao, Bo Yu, Shuanhong Ma, Daniele Dini and Feng Zhou*, 
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引用次数: 0

摘要

软骨在正常负荷下的液体渗出可以通过滑动引起的补水现象来抵消,这种现象与接触入口处的楔形效应有关,是一种流体力学现象。与软骨类似,水凝胶也具有摩擦学再水化特性,我们模仿这种现象来恢复水合润滑并克服蠕变。这种现象发生在特定的速度范围内,主要取决于外加载荷和水凝胶网络结构。最重要的是,在混合润滑状态下,一定的速度可在楔形处产生流体动力压力峰值,并驱动补水流入以克服挤压。在边界润滑状态下的较低滑动速度下,流入量不足以抵消流体渗出,而在流体动力润滑状态下的较高速度下,入口楔效应会减弱。这些结果表明,摩擦学再水化为提高水凝胶的承载能力和保持润滑提供了一种新方法。
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Sliding-Induced Rehydration in Hydrogels for Restoring Lubrication and Anticreeping Capability

Fluid exudation in cartilage under normal loading can be counteracted by a sliding-induced rehydration phenomenon, which has a hydrodynamic origin related to a wedge effect at the contact inlet. Similar to cartilage, hydrogels also exhibit tribological rehydration properties, and we mimic this phenomenon to restore hydration lubrication and overcome creeping. It occurs within a specific velocity range and is mainly dependent on the applied load and hydrogel network structures. Crucially, a certain velocity in the mixed lubrication regime can produce a hydrodynamic pressure peak at the wedge and drive the rehydration inflow to overcome the extrusion. At lower sliding velocities in the boundary lubrication regime, inflows are insufficient to counteract fluid exudation, whereas at higher velocities in the hydrodynamic lubrication regime, the inlet wedge effect would diminish. These results suggest that tribological rehydration offers a novel approach to enhancing load-bearing capacity and maintaining lubrication in the hydrogels.

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来源期刊
The Journal of Physical Chemistry Letters
The Journal of Physical Chemistry Letters CHEMISTRY, PHYSICAL-NANOSCIENCE & NANOTECHNOLOGY
CiteScore
9.60
自引率
7.00%
发文量
1519
审稿时长
1.6 months
期刊介绍: The Journal of Physical Chemistry (JPC) Letters is devoted to reporting new and original experimental and theoretical basic research of interest to physical chemists, biophysical chemists, chemical physicists, physicists, material scientists, and engineers. An important criterion for acceptance is that the paper reports a significant scientific advance and/or physical insight such that rapid publication is essential. Two issues of JPC Letters are published each month.
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