{"title":"封面：ZnR2/(AlCp*)4异种金属组合的还原-转金属反应及其在二氧化碳插入中的应用（欧洲分子化学杂志 31/2024）","authors":"Prof. Dr. Eva Hevia, Dr. Fabian Dankert","doi":"10.1002/ejic.202483101","DOIUrl":null,"url":null,"abstract":"<p><b>The Front Cover</b> shows a gull on a beautiful sunset flying with a series of smaller cartoonish gulls. In between these gulls, the ingredients for a novel reductive transmetalation route are provided: “AlCp*” and ZnR<sub>2</sub> (R=aryl), which selectively react to yield compounds of the generic formula [AlCp*R<sub>2</sub>]. As an example, a crystal structure is shown that spreads its newly introduced aryl rings as wings to fly with the big gull. Corroborated by quantum chemical calculations, such compounds found application for selective CO<sub>2</sub> insertion in their AlCp* moieties to yield small inorganic rings. More information can be found in the Research Article by E. Hevia and F. M. Dankert.\n <figure>\n <div><picture>\n <source></source></picture><p></p>\n </div>\n </figure>\n </p>","PeriodicalId":38,"journal":{"name":"European Journal of Inorganic Chemistry","volume":"27 31","pages":""},"PeriodicalIF":2.2000,"publicationDate":"2024-11-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ejic.202483101","citationCount":"0","resultStr":"{\"title\":\"Front Cover: Reductive-Transmetalation Reactions of ZnR2/(AlCp*)4 Heterobimetallic Combinations and Application Towards CO2 Insertion (Eur. J. Inorg. Chem. 31/2024)\",\"authors\":\"Prof. Dr. Eva Hevia, Dr. Fabian Dankert\",\"doi\":\"10.1002/ejic.202483101\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><b>The Front Cover</b> shows a gull on a beautiful sunset flying with a series of smaller cartoonish gulls. In between these gulls, the ingredients for a novel reductive transmetalation route are provided: “AlCp*” and ZnR<sub>2</sub> (R=aryl), which selectively react to yield compounds of the generic formula [AlCp*R<sub>2</sub>]. As an example, a crystal structure is shown that spreads its newly introduced aryl rings as wings to fly with the big gull. Corroborated by quantum chemical calculations, such compounds found application for selective CO<sub>2</sub> insertion in their AlCp* moieties to yield small inorganic rings. More information can be found in the Research Article by E. Hevia and F. M. Dankert.\\n <figure>\\n <div><picture>\\n <source></source></picture><p></p>\\n </div>\\n </figure>\\n </p>\",\"PeriodicalId\":38,\"journal\":{\"name\":\"European Journal of Inorganic Chemistry\",\"volume\":\"27 31\",\"pages\":\"\"},\"PeriodicalIF\":2.2000,\"publicationDate\":\"2024-11-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ejic.202483101\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"European Journal of Inorganic Chemistry\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/ejic.202483101\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"European Journal of Inorganic Chemistry","FirstCategoryId":"1","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ejic.202483101","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
摘要
封面展示了一只海鸥在美丽的夕阳下与一系列较小的卡通海鸥一起飞翔。在这些海鸥之间，提供了一种新型还原转金属路线的成分："AlCp*"和 ZnR2（R=芳基），它们选择性地反应生成通式为 [AlCp*R2] 的化合物。例如，图中所示的晶体结构将新引入的芳基环张开，就像展翅高飞的大海鸥。量子化学计算证实，这种化合物可用于在其 AlCp* 分子中选择性地插入二氧化碳，从而生成小型无机环。更多信息，请参阅 E. Hevia 和 F. M. Dankert 的研究文章。Dankert 的研究文章中。
Front Cover: Reductive-Transmetalation Reactions of ZnR2/(AlCp*)4 Heterobimetallic Combinations and Application Towards CO2 Insertion (Eur. J. Inorg. Chem. 31/2024)
The Front Cover shows a gull on a beautiful sunset flying with a series of smaller cartoonish gulls. In between these gulls, the ingredients for a novel reductive transmetalation route are provided: “AlCp*” and ZnR2 (R=aryl), which selectively react to yield compounds of the generic formula [AlCp*R2]. As an example, a crystal structure is shown that spreads its newly introduced aryl rings as wings to fly with the big gull. Corroborated by quantum chemical calculations, such compounds found application for selective CO2 insertion in their AlCp* moieties to yield small inorganic rings. More information can be found in the Research Article by E. Hevia and F. M. Dankert.
期刊介绍：
The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies.
The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry:
Chemische Berichte
Bulletin des Sociétés Chimiques Belges
Bulletin de la Société Chimique de France
Gazzetta Chimica Italiana
Recueil des Travaux Chimiques des Pays-Bas
Anales de Química
Chimika Chronika
Revista Portuguesa de Química
ACH—Models in Chemistry
Polish Journal of Chemistry
The European Journal of Inorganic Chemistry continues to keep you up-to-date with important inorganic chemistry research results.
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