Hu Li, Xiaoqing Wang, Zhen Guo, Zhenfeng Li, Wenmin Wang, Peng Fu, Xiucheng Fu
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引用次数: 0
摘要
以植物油为基础的橡胶复合材料正得到越来越多的开发，因为这些材料大大减少了橡胶制品中作为增塑剂的石油基致癌油的使用。除可再生性外，植物油还具有极性基团、双键和长烷基链等官能团，可使橡胶性能更加全面，使加工油从石油基的 "一剂多能 "转变为生物基的 "一剂多能"。在这项工作中，我们选择了一种生物基植物油（FN-B17）作为天然橡胶（NR）复合材料的绿色加工助剂，并选择石油基油（PB-1,2,3,4,5）进行对比研究。系统研究了 FN-B17 和其他增塑剂对复合材料的增塑作用。具体而言，研究了使用各种油的复合材料的门尼粘度、加工性能和交联特性，同时还评估了其机械性能和 RPA 动态行为。结果表明，生物基油对 NR 复合材料的加工性能和机械性能的影响与石油基油相似，甚至更好，而且生物基油可再生，成本较低，是一种经济高效的绿色加工油，可替代石油基油用于 NR 复合材料。不久的将来，利用生物基油的趋势可能会以环境可接受和可持续的方式大大提高填充橡胶复合材料的性能。
Application of bio-based vegetable oils as processing aids in industrial natural rubber composites
Rubber composites based on vegetable oils are being increasingly developed as these materials significantly reduce the use of petroleum-based carcinogenic oils as plasticisers in rubber products. Apart from renewability, vegetable oils have some functional groups such as polar group, double bond and long alkyl chain, which could make rubber performance more comprehensive, making processing oil from petroleum-based “one agent for one function” to bio-based “one agent for multiple functions”. In this work, we selected one bio-based vegetable oil (FN-B17) as green processing aid for nature rubber (NR) composites and petroleum-based oils (PB-1,2,3,4,5) were also chosen to be investigated for comparison. The plasticisation effects of FN-B17 and other plasticisers on composites were systematically studied. In specific, Mooney viscosity, processing properties and cross-linking characteristics of composites with various kinds of oils were characterised while the mechanical properties and RPA dynamic behaviors were also evaluated. The results indicated that the performance of bio-based oil on processing and mechanical properties of NR composites are similar or even better than that of petroleum-based oils, whereas bio-based oil is renewable with lower cost, which would be cost-effective green processing oil that could replace petroleum-based oil for NR composites. Soon, the trend of utilising bio-based oil may bring considerable advancements in the performance of filled rubber composites in an environmentally acceptable and sustainable manner.
期刊介绍：
The Journal of Rubber Research is devoted to both natural and synthetic rubbers, as well as to related disciplines. The scope of the journal encompasses all aspects of rubber from the core disciplines of biology, physics and chemistry, as well as economics. As a specialised field, rubber science includes within its niche a vast potential of innovative and value-added research areas yet to be explored. This peer reviewed publication focuses on the results of active experimental research and authoritative reviews on all aspects of rubber science.
The Journal of Rubber Research welcomes research on:
the upstream, including crop management, crop improvement and protection, and biotechnology;
the midstream, including processing and effluent management;
the downstream, including rubber engineering and product design, advanced rubber technology, latex science and technology, and chemistry and materials exploratory;
economics, including the economics of rubber production, consumption, and market analysis.
The Journal of Rubber Research serves to build a collective knowledge base while communicating information and validating the quality of research within the discipline, and bringing together work from experts in rubber science and related disciplines.
Scientists in both academia and industry involved in researching and working with all aspects of rubber will find this journal to be both source of information and a gateway for their own publications.
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