Di Yuan , Yafu Jiang , Wenyu Du , Dongwei Ma , Ke Chu
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Efficient urea electrosynthesis from nitrite and CO2 reduction on single W atom catalyst
Electroreduction of CO2 and NO2− to urea (ECNU) provides a fascinating method for concurrently migrating polluted NO2− and producing value-added urea. In this study, atomically dispersed W on MoS2 (W1/MoS2) is designed as an efficient ECNU catalyst, which exhibits the highest Faraday efficiency of 60.11 % and urea yield rate of 35.80 mmol h−1 g−1 in flow cell. Atomic characterizations reveal that W single atoms exist as isolated W1-S3 moieties on MoS2. Combined theoretical calculations and operando spectroscopic measurements demonstrate that the enhanced ECNU performance of W1/MoS2 arises from the construction of W1-S3 moieties that can promote CN coupling and hydrogenation energetics, whilst suppressing the competing side reactions.
期刊介绍：
The Journal of Colloid and Interface Science publishes original research findings on the fundamental principles of colloid and interface science, as well as innovative applications in various fields. The criteria for publication include impact, quality, novelty, and originality.
Emphasis:
The journal emphasizes fundamental scientific innovation within the following categories:
A.Colloidal Materials and Nanomaterials
B.Soft Colloidal and Self-Assembly Systems
C.Adsorption, Catalysis, and Electrochemistry
D.Interfacial Processes, Capillarity, and Wetting
E.Biomaterials and Nanomedicine
F.Energy Conversion and Storage, and Environmental Technologies
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