利用铜铁氧体磁性纳米粒子辅助的批次型吸附去除策略去除合成废水样品中的镉离子。

IF 2.9 4区 环境科学与生态学 Q3 ENVIRONMENTAL SCIENCES Environmental Monitoring and Assessment Pub Date : 2024-11-18 DOI:10.1007/s10661-024-13408-1
Buse Tuğba Zaman, Hilal Akbıyık, Ayça Girgin, Gamze Dalgıç Bozyiğit, Emine Gülhan Bakırdere, Sezgin Bakırdere
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引用次数: 0

摘要

工业活动会向环境排放各种有害物质,包括有机和无机成分。如果处理不当,将这些污染物排放到水生环境中,可能会产生不良影响。镉(Cd)是一种有毒元素,存在于各种人为和地质环境来源中,会污染土壤和地下水,而土壤和地下水对提供健康食品和安全饮用水至关重要。本研究旨在开发一种新型策略,借助纳米吸附剂,通过间歇式吸附过程去除废水中的镉离子。研究人员采用共沉淀工艺合成了具有高磁性的 CuFe2O4 纳米粒子,用于高效去除分析物。利用场发射扫描电子显微镜(FE-SEM)、X 射线衍射(XRD)和布鲁纳尔-艾美特-泰勒(BET)分析法对纳米材料进行了表征。通过单变量实验对方法的有效参数进行了系统优化,以找到改善吸附剂与镉离子之间相互作用的适当条件。利用合成废水样品评估了镉的去除率(%RE),在火焰原子吸收分光光度法(FAAS)的线性范围内,所推荐方法的准确性/实用性被证明是高效的。此外,还将 Langmuir 等温线模型应用于实验数据,证明了磁性 CuFe2O4 纳米粒子对合成废水中镉的有效吸附。
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Removal of cadmium ions from synthetic wastewater samples by copper ferrite magnetic nanoparticle–assisted batch-type adsorption-based removal strategy

Industrial activities can release a variety of harmful substances, including organic and inorganic components, into the environment. Inadequate treatment and discharge of these pollutants into aquatic environments might have adverse effects. Cadmium (Cd) is a toxic element found in various environmental sources, both anthropogenic and geogenic, which can contaminate soils and groundwater crucial for providing healthy food and safe drinking water. This study aimed to develop a novel strategy by the help of nano-sized adsorbents to remove cadmium ions from wastewater through batch-type adsorption processes. CuFe2O4 nanoparticles having high magnetic properties were synthesized using a co-precipitation process for the efficient removal of analyte. Characterization of the nanomaterial was performed using field emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), and Brunauer–Emmett–Teller (BET) analysis. Method effective parameters were systematically optimized through univariate experiments to find proper conditions for the improvement of interaction between the adsorbent and cadmium ions. Removal efficiency (%RE) of Cd was assessed by using synthetic wastewater samples, and the accuracy/practicability of the recommended method proved highly efficient within the linear range of flame atomic absorption spectrophotometry (FAAS). In addition, the Langmuir isotherm model was applied to the experimental data, and the effective adsorption of cadmium from synthetic wastewater by the magnetic CuFe2O4 nanoparticles was proved.

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来源期刊
Environmental Monitoring and Assessment
Environmental Monitoring and Assessment 环境科学-环境科学
CiteScore
4.70
自引率
6.70%
发文量
1000
审稿时长
7.3 months
期刊介绍: Environmental Monitoring and Assessment emphasizes technical developments and data arising from environmental monitoring and assessment, the use of scientific principles in the design of monitoring systems at the local, regional and global scales, and the use of monitoring data in assessing the consequences of natural resource management actions and pollution risks to man and the environment.
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