Jian Li , Shuai-Bing Ma , De-Sheng Wei , Wan-Yi Lan , Ting-Ting Xu , Yu-Teng Zhang , Nan Lv , Shuang-Bao Li
{"title":"三氟甲基功能化锆基金属有机笼 (ZrT-(CF3)2)：去除水杨酸的高效吸附剂","authors":"Jian Li , Shuai-Bing Ma , De-Sheng Wei , Wan-Yi Lan , Ting-Ting Xu , Yu-Teng Zhang , Nan Lv , Shuang-Bao Li","doi":"10.1016/j.jssc.2024.125098","DOIUrl":null,"url":null,"abstract":"<div><div>Herein, a novel CF<sub>3</sub>-functionalized zirconium-based metal-organic tetrahedron (ZrT-(CF<sub>3</sub>)<sub>2</sub>) was constructed based on 2.5-bis(trifluoromethyl)terephthalic acid (H<sub>2</sub>BDC-(CF<sub>3</sub>)<sub>2</sub>) ligand and trinuclear zirconocene building unit. Notably, the single crystals of ZrT-(CF<sub>3</sub>)<sub>2</sub> was obtained under traditional solvothermal condition, while the yield and purity could be further improved by the microwave-assisted solvothermal method. Subsequently, the adsorption performance of ZrT-(CF<sub>3</sub>)<sub>2</sub> for salicylic acid (SA) emerging contaminant was systematically evaluated, indicating a maximum adsorption capacity of 99.91 mg/g under optimal conditions. Furthermore, a possible adsorption mechanism was proposed based on experimental results and DFT simulations.</div></div>","PeriodicalId":378,"journal":{"name":"Journal of Solid State Chemistry","volume":"341 ","pages":"Article 125098"},"PeriodicalIF":3.2000,"publicationDate":"2024-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Trifluoromethyl-functionalized zirconium-based metal-organic cage (ZrT-(CF3)2): An efficient adsorbent for salicylic acid removal\",\"authors\":\"Jian Li , Shuai-Bing Ma , De-Sheng Wei , Wan-Yi Lan , Ting-Ting Xu , Yu-Teng Zhang , Nan Lv , Shuang-Bao Li\",\"doi\":\"10.1016/j.jssc.2024.125098\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Herein, a novel CF<sub>3</sub>-functionalized zirconium-based metal-organic tetrahedron (ZrT-(CF<sub>3</sub>)<sub>2</sub>) was constructed based on 2.5-bis(trifluoromethyl)terephthalic acid (H<sub>2</sub>BDC-(CF<sub>3</sub>)<sub>2</sub>) ligand and trinuclear zirconocene building unit. Notably, the single crystals of ZrT-(CF<sub>3</sub>)<sub>2</sub> was obtained under traditional solvothermal condition, while the yield and purity could be further improved by the microwave-assisted solvothermal method. Subsequently, the adsorption performance of ZrT-(CF<sub>3</sub>)<sub>2</sub> for salicylic acid (SA) emerging contaminant was systematically evaluated, indicating a maximum adsorption capacity of 99.91 mg/g under optimal conditions. Furthermore, a possible adsorption mechanism was proposed based on experimental results and DFT simulations.</div></div>\",\"PeriodicalId\":378,\"journal\":{\"name\":\"Journal of Solid State Chemistry\",\"volume\":\"341 \",\"pages\":\"Article 125098\"},\"PeriodicalIF\":3.2000,\"publicationDate\":\"2024-11-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Solid State Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0022459624005528\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Solid State Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0022459624005528","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Trifluoromethyl-functionalized zirconium-based metal-organic cage (ZrT-(CF3)2): An efficient adsorbent for salicylic acid removal
Herein, a novel CF3-functionalized zirconium-based metal-organic tetrahedron (ZrT-(CF3)2) was constructed based on 2.5-bis(trifluoromethyl)terephthalic acid (H2BDC-(CF3)2) ligand and trinuclear zirconocene building unit. Notably, the single crystals of ZrT-(CF3)2 was obtained under traditional solvothermal condition, while the yield and purity could be further improved by the microwave-assisted solvothermal method. Subsequently, the adsorption performance of ZrT-(CF3)2 for salicylic acid (SA) emerging contaminant was systematically evaluated, indicating a maximum adsorption capacity of 99.91 mg/g under optimal conditions. Furthermore, a possible adsorption mechanism was proposed based on experimental results and DFT simulations.
期刊介绍：
Covering major developments in the field of solid state chemistry and related areas such as ceramics and amorphous materials, the Journal of Solid State Chemistry features studies of chemical, structural, thermodynamic, electronic, magnetic, and optical properties and processes in solids.
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