Ilia B. Moroz, Neta Katzav, Asya Svirinovsky-Arbeli, Michal Leskes
{"title":"材料科学中的金属离子动态核极化实用指南","authors":"Ilia B. Moroz, Neta Katzav, Asya Svirinovsky-Arbeli, Michal Leskes","doi":"10.1016/j.jmro.2024.100173","DOIUrl":null,"url":null,"abstract":"<div><div>In this protocol we outline the practical aspects and methodology for performing metal ions-based dynamic nuclear polarization (MI-DNP), focusing on materials science applications. In MI-DNP polarization is transferred from unpaired electrons of paramagnetic metal ions to nearby nuclear spins, thereby increasing the sensitivity of NMR spectroscopy. The protocol encompasses detailed steps for (i) selecting suitable metal ion dopant based on chemical, structural and electron paramagnetic resonance (EPR) considerations, (ii) characterizing the concentration, homogeneity and EPR properties of the dopant and (iii) performing the MI-DNP experiment itself, including optimization of the field position and reliable assessment of the DNP enhancement factors. By adhering to this protocol, the interested reader can implement the MI-DNP approach in an efficient way, facilitating spectroscopic studies of functional materials.</div></div>","PeriodicalId":365,"journal":{"name":"Journal of Magnetic Resonance Open","volume":"21 ","pages":"Article 100173"},"PeriodicalIF":2.6240,"publicationDate":"2024-11-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A practical guide to metal ions dynamic nuclear polarization in materials science\",\"authors\":\"Ilia B. Moroz, Neta Katzav, Asya Svirinovsky-Arbeli, Michal Leskes\",\"doi\":\"10.1016/j.jmro.2024.100173\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>In this protocol we outline the practical aspects and methodology for performing metal ions-based dynamic nuclear polarization (MI-DNP), focusing on materials science applications. In MI-DNP polarization is transferred from unpaired electrons of paramagnetic metal ions to nearby nuclear spins, thereby increasing the sensitivity of NMR spectroscopy. The protocol encompasses detailed steps for (i) selecting suitable metal ion dopant based on chemical, structural and electron paramagnetic resonance (EPR) considerations, (ii) characterizing the concentration, homogeneity and EPR properties of the dopant and (iii) performing the MI-DNP experiment itself, including optimization of the field position and reliable assessment of the DNP enhancement factors. By adhering to this protocol, the interested reader can implement the MI-DNP approach in an efficient way, facilitating spectroscopic studies of functional materials.</div></div>\",\"PeriodicalId\":365,\"journal\":{\"name\":\"Journal of Magnetic Resonance Open\",\"volume\":\"21 \",\"pages\":\"Article 100173\"},\"PeriodicalIF\":2.6240,\"publicationDate\":\"2024-11-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Magnetic Resonance Open\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2666441024000281\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Magnetic Resonance Open","FirstCategoryId":"1","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2666441024000281","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
A practical guide to metal ions dynamic nuclear polarization in materials science
In this protocol we outline the practical aspects and methodology for performing metal ions-based dynamic nuclear polarization (MI-DNP), focusing on materials science applications. In MI-DNP polarization is transferred from unpaired electrons of paramagnetic metal ions to nearby nuclear spins, thereby increasing the sensitivity of NMR spectroscopy. The protocol encompasses detailed steps for (i) selecting suitable metal ion dopant based on chemical, structural and electron paramagnetic resonance (EPR) considerations, (ii) characterizing the concentration, homogeneity and EPR properties of the dopant and (iii) performing the MI-DNP experiment itself, including optimization of the field position and reliable assessment of the DNP enhancement factors. By adhering to this protocol, the interested reader can implement the MI-DNP approach in an efficient way, facilitating spectroscopic studies of functional materials.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
