Yan Zhang , Bo-Yu Ni , Yan-Fu Chai , Wei-Ming Guo , Tian-Qi Zhang , Wei-Feng Yao , Hua-Tay Lin
{"title":"(Hf0.2Zr0.2Ta0.2Ti0.2Me0.2)B2 (Me=Nb,Cr) 高熵陶瓷在 1200 °C 空气中的氧化行为","authors":"Yan Zhang , Bo-Yu Ni , Yan-Fu Chai , Wei-Ming Guo , Tian-Qi Zhang , Wei-Feng Yao , Hua-Tay Lin","doi":"10.1016/j.jeurceramsoc.2024.117078","DOIUrl":null,"url":null,"abstract":"<div><div>The oxidation behavior of (Hf<sub>0.2</sub>Zr<sub>0.2</sub>Ta<sub>0.2</sub>Nb<sub>0.2</sub>Ti<sub>0.2</sub>)B<sub>2</sub> and (Hf<sub>0.2</sub>Zr<sub>0.2</sub>Ta<sub>0.2</sub>Cr<sub>0.2</sub>Ti<sub>0.2</sub>)B<sub>2</sub> high entropy boride ceramics at 1200 °C was investigated to provide insights into their microstructural evolution and oxidation mechanism. The results showed that the oxide layer thickness of (Hf<sub>0.2</sub>Zr<sub>0.2</sub>Ta<sub>0.2</sub>Nb<sub>0.2</sub>Ti<sub>0.2</sub>)B<sub>2</sub> was about 112 μm, much thicker than the counterpart of (Hf<sub>0.2</sub>Zr<sub>0.2</sub>Ta<sub>0.2</sub>Cr<sub>0.2</sub>Ti<sub>0.2</sub>)B<sub>2</sub> (∼62 μm). The differences in oxidation response and oxidation resistance between these two material systems were mainly pertained to the generation of different structures of oxide layer. For the (Hf<sub>0.2</sub>Zr<sub>0.2</sub>Ta<sub>0.2</sub>Nb<sub>0.2</sub>Ti<sub>0.2</sub>)B<sub>2</sub> sample, the oxide layer was composed of four-layer structure (porous-dense-porous-dense). In contrast, the oxide layers of (Hf<sub>0.2</sub>Zr<sub>0.2</sub>Ta<sub>0.2</sub>Cr<sub>0.2</sub>Ti<sub>0.2</sub>)B<sub>2</sub> sample exhibited a distinctly laminated structure.</div></div>","PeriodicalId":17408,"journal":{"name":"Journal of The European Ceramic Society","volume":"45 4","pages":"Article 117078"},"PeriodicalIF":5.8000,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Oxidation behavior of (Hf0.2Zr0.2Ta0.2Ti0.2Me0.2)B2 (Me=Nb,Cr) high-entropy ceramics at 1200 °C in air\",\"authors\":\"Yan Zhang , Bo-Yu Ni , Yan-Fu Chai , Wei-Ming Guo , Tian-Qi Zhang , Wei-Feng Yao , Hua-Tay Lin\",\"doi\":\"10.1016/j.jeurceramsoc.2024.117078\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The oxidation behavior of (Hf<sub>0.2</sub>Zr<sub>0.2</sub>Ta<sub>0.2</sub>Nb<sub>0.2</sub>Ti<sub>0.2</sub>)B<sub>2</sub> and (Hf<sub>0.2</sub>Zr<sub>0.2</sub>Ta<sub>0.2</sub>Cr<sub>0.2</sub>Ti<sub>0.2</sub>)B<sub>2</sub> high entropy boride ceramics at 1200 °C was investigated to provide insights into their microstructural evolution and oxidation mechanism. The results showed that the oxide layer thickness of (Hf<sub>0.2</sub>Zr<sub>0.2</sub>Ta<sub>0.2</sub>Nb<sub>0.2</sub>Ti<sub>0.2</sub>)B<sub>2</sub> was about 112 μm, much thicker than the counterpart of (Hf<sub>0.2</sub>Zr<sub>0.2</sub>Ta<sub>0.2</sub>Cr<sub>0.2</sub>Ti<sub>0.2</sub>)B<sub>2</sub> (∼62 μm). The differences in oxidation response and oxidation resistance between these two material systems were mainly pertained to the generation of different structures of oxide layer. For the (Hf<sub>0.2</sub>Zr<sub>0.2</sub>Ta<sub>0.2</sub>Nb<sub>0.2</sub>Ti<sub>0.2</sub>)B<sub>2</sub> sample, the oxide layer was composed of four-layer structure (porous-dense-porous-dense). In contrast, the oxide layers of (Hf<sub>0.2</sub>Zr<sub>0.2</sub>Ta<sub>0.2</sub>Cr<sub>0.2</sub>Ti<sub>0.2</sub>)B<sub>2</sub> sample exhibited a distinctly laminated structure.</div></div>\",\"PeriodicalId\":17408,\"journal\":{\"name\":\"Journal of The European Ceramic Society\",\"volume\":\"45 4\",\"pages\":\"Article 117078\"},\"PeriodicalIF\":5.8000,\"publicationDate\":\"2024-11-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The European Ceramic Society\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0955221924009518\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The European Ceramic Society","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0955221924009518","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
Oxidation behavior of (Hf0.2Zr0.2Ta0.2Ti0.2Me0.2)B2 (Me=Nb,Cr) high-entropy ceramics at 1200 °C in air
The oxidation behavior of (Hf0.2Zr0.2Ta0.2Nb0.2Ti0.2)B2 and (Hf0.2Zr0.2Ta0.2Cr0.2Ti0.2)B2 high entropy boride ceramics at 1200 °C was investigated to provide insights into their microstructural evolution and oxidation mechanism. The results showed that the oxide layer thickness of (Hf0.2Zr0.2Ta0.2Nb0.2Ti0.2)B2 was about 112 μm, much thicker than the counterpart of (Hf0.2Zr0.2Ta0.2Cr0.2Ti0.2)B2 (∼62 μm). The differences in oxidation response and oxidation resistance between these two material systems were mainly pertained to the generation of different structures of oxide layer. For the (Hf0.2Zr0.2Ta0.2Nb0.2Ti0.2)B2 sample, the oxide layer was composed of four-layer structure (porous-dense-porous-dense). In contrast, the oxide layers of (Hf0.2Zr0.2Ta0.2Cr0.2Ti0.2)B2 sample exhibited a distinctly laminated structure.
期刊介绍：
The Journal of the European Ceramic Society publishes the results of original research and reviews relating to ceramic materials. Papers of either an experimental or theoretical character will be welcomed on a fully international basis. The emphasis is on novel generic science concerning the relationships between processing, microstructure and properties of polycrystalline ceramics consolidated at high temperature. Papers may relate to any of the conventional categories of ceramic: structural, functional, traditional or composite. The central objective is to sustain a high standard of research quality by means of appropriate reviewing procedures.
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