{"title":"金（I）-N-杂环碳烯配合物的光致发光特性","authors":"Sunusi Y. Hussaini , Mohd R. Razali","doi":"10.1016/j.molstruc.2024.140614","DOIUrl":null,"url":null,"abstract":"<div><div>Gold(I)-<em>N</em>-heterocyclic carbenes (NHCs) complexes have undergone rapid development and developed as useful tools for the design of various scaffolds in diverse applications such as biological, catalytic and photophysical applications. This review covers photoluminescence transition properties of gold complexes containing NHC ligands, which give resulted in high energy emissions with desired blue colour needs for new optical devices, bioimaging and organic light emitting diodes (OLEDs). In addition, the great versatility in the structural morphology of the complexes with aurophilic interactions, provides numerous possibilities in the synthesis of desired luminescence complexes with lifetimes corresponding to a fluorescence or phosphorescence process that depends on the origin of the emissions. Herein, we present an overview on structural and electronic properties of NHC ligand, metal-NHC complexes, gold(I)-NHC complexes and photoluminescence properties reported from various research works.</div></div>","PeriodicalId":16414,"journal":{"name":"Journal of Molecular Structure","volume":"1322 ","pages":"Article 140614"},"PeriodicalIF":4.0000,"publicationDate":"2024-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Photoluminescence properties of Gold(I)-N-Heterocyclic carbene complexes\",\"authors\":\"Sunusi Y. Hussaini , Mohd R. Razali\",\"doi\":\"10.1016/j.molstruc.2024.140614\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Gold(I)-<em>N</em>-heterocyclic carbenes (NHCs) complexes have undergone rapid development and developed as useful tools for the design of various scaffolds in diverse applications such as biological, catalytic and photophysical applications. This review covers photoluminescence transition properties of gold complexes containing NHC ligands, which give resulted in high energy emissions with desired blue colour needs for new optical devices, bioimaging and organic light emitting diodes (OLEDs). In addition, the great versatility in the structural morphology of the complexes with aurophilic interactions, provides numerous possibilities in the synthesis of desired luminescence complexes with lifetimes corresponding to a fluorescence or phosphorescence process that depends on the origin of the emissions. Herein, we present an overview on structural and electronic properties of NHC ligand, metal-NHC complexes, gold(I)-NHC complexes and photoluminescence properties reported from various research works.</div></div>\",\"PeriodicalId\":16414,\"journal\":{\"name\":\"Journal of Molecular Structure\",\"volume\":\"1322 \",\"pages\":\"Article 140614\"},\"PeriodicalIF\":4.0000,\"publicationDate\":\"2024-11-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Molecular Structure\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0022286024031223\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Molecular Structure","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0022286024031223","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Photoluminescence properties of Gold(I)-N-Heterocyclic carbene complexes
Gold(I)-N-heterocyclic carbenes (NHCs) complexes have undergone rapid development and developed as useful tools for the design of various scaffolds in diverse applications such as biological, catalytic and photophysical applications. This review covers photoluminescence transition properties of gold complexes containing NHC ligands, which give resulted in high energy emissions with desired blue colour needs for new optical devices, bioimaging and organic light emitting diodes (OLEDs). In addition, the great versatility in the structural morphology of the complexes with aurophilic interactions, provides numerous possibilities in the synthesis of desired luminescence complexes with lifetimes corresponding to a fluorescence or phosphorescence process that depends on the origin of the emissions. Herein, we present an overview on structural and electronic properties of NHC ligand, metal-NHC complexes, gold(I)-NHC complexes and photoluminescence properties reported from various research works.
期刊介绍：
The Journal of Molecular Structure is dedicated to the publication of full-length articles and review papers, providing important new structural information on all types of chemical species including:
• Stable and unstable molecules in all types of environments (vapour, molecular beam, liquid, solution, liquid crystal, solid state, matrix-isolated, surface-absorbed etc.)
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