Annette Jayam Somasundaram, Elaiyappillai Elanthamilan, Sea-Fue Wang, I. Sharmila Lydia
{"title":"构建具有增强可见光驱动光催化活性的磁性 Ag3PO4/Fe3O4/Chitosan 聚合物,用于降解亚甲基蓝染料","authors":"Annette Jayam Somasundaram, Elaiyappillai Elanthamilan, Sea-Fue Wang, I. Sharmila Lydia","doi":"10.1007/s10924-024-03375-6","DOIUrl":null,"url":null,"abstract":"<div><p>The present study employed the simple co-precipitation approach followed by ultrasonication to generate a composite material consisting of magnetic Ag<sub>3</sub>PO<sub>4</sub>/Fe<sub>3</sub>O<sub>4</sub>/Chitosan(CS). The magnetic Ag<sub>3</sub>PO<sub>4</sub>/Fe<sub>3</sub>O<sub>4</sub>/CS composite was characterized using the Fourier transform infrared (FTIR), scanning electron microscopy (SEM), X-ray diffraction (XRD), vibrating sample magnetometer (VSM), and X-ray photoelectron spectroscopy (XPS) methods. The magnetic composite was evaluated as a photocatalyst for methylene blue (MB) degradation under visible light irradiation. The investigation also focused on optimizing the photocatalyst dose, concentration fluctuation, and stability to enhance the reaction conditions for dye degradation. The magnetic Ag<sub>3</sub>PO<sub>4</sub>/Fe<sub>3</sub>O<sub>4</sub>/CS composite exhibited robust photocatalytic activity for the degradation of MB, with a removal efficiency of 95%. Furthermore, the recyclability of the magnetic composite was evaluated for five successive cycles and the degradation efficiency was reduced to 85% only, demonstrating its robustness. The composite demonstrated exceptional recyclability and reusability while experiencing no degradation in catalytic activity. The results of this study will aid in the advancement of environmentally friendly nanotechnology by enabling the production of easily separable magnetic Ag<sub>3</sub>PO<sub>4</sub>/Fe<sub>3</sub>O<sub>4</sub>/CS composite as heterogeneous catalysts.</p></div>","PeriodicalId":659,"journal":{"name":"Journal of Polymers and the Environment","volume":"32 12","pages":"6650 - 6666"},"PeriodicalIF":4.7000,"publicationDate":"2024-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Construction of Magnetic Ag3PO4/Fe3O4/Chitosan Polymer Composite with Enhanced Visible-light-driven Photocatalytic Activity for the Methylene Blue Dye Degradation\",\"authors\":\"Annette Jayam Somasundaram, Elaiyappillai Elanthamilan, Sea-Fue Wang, I. Sharmila Lydia\",\"doi\":\"10.1007/s10924-024-03375-6\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The present study employed the simple co-precipitation approach followed by ultrasonication to generate a composite material consisting of magnetic Ag<sub>3</sub>PO<sub>4</sub>/Fe<sub>3</sub>O<sub>4</sub>/Chitosan(CS). The magnetic Ag<sub>3</sub>PO<sub>4</sub>/Fe<sub>3</sub>O<sub>4</sub>/CS composite was characterized using the Fourier transform infrared (FTIR), scanning electron microscopy (SEM), X-ray diffraction (XRD), vibrating sample magnetometer (VSM), and X-ray photoelectron spectroscopy (XPS) methods. The magnetic composite was evaluated as a photocatalyst for methylene blue (MB) degradation under visible light irradiation. The investigation also focused on optimizing the photocatalyst dose, concentration fluctuation, and stability to enhance the reaction conditions for dye degradation. The magnetic Ag<sub>3</sub>PO<sub>4</sub>/Fe<sub>3</sub>O<sub>4</sub>/CS composite exhibited robust photocatalytic activity for the degradation of MB, with a removal efficiency of 95%. Furthermore, the recyclability of the magnetic composite was evaluated for five successive cycles and the degradation efficiency was reduced to 85% only, demonstrating its robustness. The composite demonstrated exceptional recyclability and reusability while experiencing no degradation in catalytic activity. The results of this study will aid in the advancement of environmentally friendly nanotechnology by enabling the production of easily separable magnetic Ag<sub>3</sub>PO<sub>4</sub>/Fe<sub>3</sub>O<sub>4</sub>/CS composite as heterogeneous catalysts.</p></div>\",\"PeriodicalId\":659,\"journal\":{\"name\":\"Journal of Polymers and the Environment\",\"volume\":\"32 12\",\"pages\":\"6650 - 6666\"},\"PeriodicalIF\":4.7000,\"publicationDate\":\"2024-09-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Polymers and the Environment\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10924-024-03375-6\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENGINEERING, ENVIRONMENTAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Polymers and the Environment","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s10924-024-03375-6","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, ENVIRONMENTAL","Score":null,"Total":0}
Construction of Magnetic Ag3PO4/Fe3O4/Chitosan Polymer Composite with Enhanced Visible-light-driven Photocatalytic Activity for the Methylene Blue Dye Degradation
The present study employed the simple co-precipitation approach followed by ultrasonication to generate a composite material consisting of magnetic Ag3PO4/Fe3O4/Chitosan(CS). The magnetic Ag3PO4/Fe3O4/CS composite was characterized using the Fourier transform infrared (FTIR), scanning electron microscopy (SEM), X-ray diffraction (XRD), vibrating sample magnetometer (VSM), and X-ray photoelectron spectroscopy (XPS) methods. The magnetic composite was evaluated as a photocatalyst for methylene blue (MB) degradation under visible light irradiation. The investigation also focused on optimizing the photocatalyst dose, concentration fluctuation, and stability to enhance the reaction conditions for dye degradation. The magnetic Ag3PO4/Fe3O4/CS composite exhibited robust photocatalytic activity for the degradation of MB, with a removal efficiency of 95%. Furthermore, the recyclability of the magnetic composite was evaluated for five successive cycles and the degradation efficiency was reduced to 85% only, demonstrating its robustness. The composite demonstrated exceptional recyclability and reusability while experiencing no degradation in catalytic activity. The results of this study will aid in the advancement of environmentally friendly nanotechnology by enabling the production of easily separable magnetic Ag3PO4/Fe3O4/CS composite as heterogeneous catalysts.
期刊介绍:
The Journal of Polymers and the Environment fills the need for an international forum in this diverse and rapidly expanding field. The journal serves a crucial role for the publication of information from a wide range of disciplines and is a central outlet for the publication of high-quality peer-reviewed original papers, review articles and short communications. The journal is intentionally interdisciplinary in regard to contributions and covers the following subjects - polymers, environmentally degradable polymers, and degradation pathways: biological, photochemical, oxidative and hydrolytic; new environmental materials: derived by chemical and biosynthetic routes; environmental blends and composites; developments in processing and reactive processing of environmental polymers; characterization of environmental materials: mechanical, physical, thermal, rheological, morphological, and others; recyclable polymers and plastics recycling environmental testing: in-laboratory simulations, outdoor exposures, and standardization of methodologies; environmental fate: end products and intermediates of biodegradation; microbiology and enzymology of polymer biodegradation; solid-waste management and public legislation specific to environmental polymers; and other related topics.