构建具有增强可见光驱动光催化活性的磁性 Ag3PO4/Fe3O4/Chitosan 聚合物,用于降解亚甲基蓝染料

IF 4.7 3区 工程技术 Q2 ENGINEERING, ENVIRONMENTAL Journal of Polymers and the Environment Pub Date : 2024-09-23 DOI:10.1007/s10924-024-03375-6
Annette Jayam Somasundaram, Elaiyappillai Elanthamilan, Sea-Fue Wang, I. Sharmila Lydia
{"title":"构建具有增强可见光驱动光催化活性的磁性 Ag3PO4/Fe3O4/Chitosan 聚合物,用于降解亚甲基蓝染料","authors":"Annette Jayam Somasundaram,&nbsp;Elaiyappillai Elanthamilan,&nbsp;Sea-Fue Wang,&nbsp;I. Sharmila Lydia","doi":"10.1007/s10924-024-03375-6","DOIUrl":null,"url":null,"abstract":"<div><p>The present study employed the simple co-precipitation approach followed by ultrasonication to generate a composite material consisting of magnetic Ag<sub>3</sub>PO<sub>4</sub>/Fe<sub>3</sub>O<sub>4</sub>/Chitosan(CS). The magnetic Ag<sub>3</sub>PO<sub>4</sub>/Fe<sub>3</sub>O<sub>4</sub>/CS composite was characterized using the Fourier transform infrared (FTIR), scanning electron microscopy (SEM), X-ray diffraction (XRD), vibrating sample magnetometer (VSM), and X-ray photoelectron spectroscopy (XPS) methods. The magnetic composite was evaluated as a photocatalyst for methylene blue (MB) degradation under visible light irradiation. The investigation also focused on optimizing the photocatalyst dose, concentration fluctuation, and stability to enhance the reaction conditions for dye degradation. The magnetic Ag<sub>3</sub>PO<sub>4</sub>/Fe<sub>3</sub>O<sub>4</sub>/CS composite exhibited robust photocatalytic activity for the degradation of MB, with a removal efficiency of 95%. Furthermore, the recyclability of the magnetic composite was evaluated for five successive cycles and the degradation efficiency was reduced to 85% only, demonstrating its robustness. The composite demonstrated exceptional recyclability and reusability while experiencing no degradation in catalytic activity. The results of this study will aid in the advancement of environmentally friendly nanotechnology by enabling the production of easily separable magnetic Ag<sub>3</sub>PO<sub>4</sub>/Fe<sub>3</sub>O<sub>4</sub>/CS composite as heterogeneous catalysts.</p></div>","PeriodicalId":659,"journal":{"name":"Journal of Polymers and the Environment","volume":"32 12","pages":"6650 - 6666"},"PeriodicalIF":4.7000,"publicationDate":"2024-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Construction of Magnetic Ag3PO4/Fe3O4/Chitosan Polymer Composite with Enhanced Visible-light-driven Photocatalytic Activity for the Methylene Blue Dye Degradation\",\"authors\":\"Annette Jayam Somasundaram,&nbsp;Elaiyappillai Elanthamilan,&nbsp;Sea-Fue Wang,&nbsp;I. Sharmila Lydia\",\"doi\":\"10.1007/s10924-024-03375-6\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The present study employed the simple co-precipitation approach followed by ultrasonication to generate a composite material consisting of magnetic Ag<sub>3</sub>PO<sub>4</sub>/Fe<sub>3</sub>O<sub>4</sub>/Chitosan(CS). The magnetic Ag<sub>3</sub>PO<sub>4</sub>/Fe<sub>3</sub>O<sub>4</sub>/CS composite was characterized using the Fourier transform infrared (FTIR), scanning electron microscopy (SEM), X-ray diffraction (XRD), vibrating sample magnetometer (VSM), and X-ray photoelectron spectroscopy (XPS) methods. The magnetic composite was evaluated as a photocatalyst for methylene blue (MB) degradation under visible light irradiation. The investigation also focused on optimizing the photocatalyst dose, concentration fluctuation, and stability to enhance the reaction conditions for dye degradation. The magnetic Ag<sub>3</sub>PO<sub>4</sub>/Fe<sub>3</sub>O<sub>4</sub>/CS composite exhibited robust photocatalytic activity for the degradation of MB, with a removal efficiency of 95%. Furthermore, the recyclability of the magnetic composite was evaluated for five successive cycles and the degradation efficiency was reduced to 85% only, demonstrating its robustness. The composite demonstrated exceptional recyclability and reusability while experiencing no degradation in catalytic activity. The results of this study will aid in the advancement of environmentally friendly nanotechnology by enabling the production of easily separable magnetic Ag<sub>3</sub>PO<sub>4</sub>/Fe<sub>3</sub>O<sub>4</sub>/CS composite as heterogeneous catalysts.</p></div>\",\"PeriodicalId\":659,\"journal\":{\"name\":\"Journal of Polymers and the Environment\",\"volume\":\"32 12\",\"pages\":\"6650 - 6666\"},\"PeriodicalIF\":4.7000,\"publicationDate\":\"2024-09-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Polymers and the Environment\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10924-024-03375-6\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENGINEERING, ENVIRONMENTAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Polymers and the Environment","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s10924-024-03375-6","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, ENVIRONMENTAL","Score":null,"Total":0}
引用次数: 0

摘要

本研究采用简单的共沉淀方法,然后用超声波处理生成了一种由磁性 Ag3PO4/Fe3O4/Chitosan(CS) 组成的复合材料。利用傅立叶变换红外(FTIR)、扫描电子显微镜(SEM)、X 射线衍射(XRD)、振动样品磁力计(VSM)和 X 射线光电子能谱(XPS)方法对磁性 Ag3PO4/Fe3O4/CS 复合材料进行了表征。该磁性复合材料被评估为一种光催化剂,可在可见光照射下降解亚甲基蓝(MB)。研究还侧重于优化光催化剂的剂量、浓度波动和稳定性,以改善染料降解的反应条件。磁性 Ag3PO4/Fe3O4/CS 复合材料在降解甲基溴方面表现出很强的光催化活性,去除效率高达 95%。此外,对磁性复合材料的可回收性进行了连续五个周期的评估,降解效率仅降低到 85%,这证明了它的稳健性。该复合材料表现出卓越的可回收性和可再利用性,同时催化活性没有下降。这项研究的结果将有助于生产易于分离的磁性 Ag3PO4/Fe3O4/CS 复合材料作为异相催化剂,从而推动环境友好型纳米技术的发展。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Construction of Magnetic Ag3PO4/Fe3O4/Chitosan Polymer Composite with Enhanced Visible-light-driven Photocatalytic Activity for the Methylene Blue Dye Degradation

The present study employed the simple co-precipitation approach followed by ultrasonication to generate a composite material consisting of magnetic Ag3PO4/Fe3O4/Chitosan(CS). The magnetic Ag3PO4/Fe3O4/CS composite was characterized using the Fourier transform infrared (FTIR), scanning electron microscopy (SEM), X-ray diffraction (XRD), vibrating sample magnetometer (VSM), and X-ray photoelectron spectroscopy (XPS) methods. The magnetic composite was evaluated as a photocatalyst for methylene blue (MB) degradation under visible light irradiation. The investigation also focused on optimizing the photocatalyst dose, concentration fluctuation, and stability to enhance the reaction conditions for dye degradation. The magnetic Ag3PO4/Fe3O4/CS composite exhibited robust photocatalytic activity for the degradation of MB, with a removal efficiency of 95%. Furthermore, the recyclability of the magnetic composite was evaluated for five successive cycles and the degradation efficiency was reduced to 85% only, demonstrating its robustness. The composite demonstrated exceptional recyclability and reusability while experiencing no degradation in catalytic activity. The results of this study will aid in the advancement of environmentally friendly nanotechnology by enabling the production of easily separable magnetic Ag3PO4/Fe3O4/CS composite as heterogeneous catalysts.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Journal of Polymers and the Environment
Journal of Polymers and the Environment 工程技术-高分子科学
CiteScore
9.50
自引率
7.50%
发文量
297
审稿时长
9 months
期刊介绍: The Journal of Polymers and the Environment fills the need for an international forum in this diverse and rapidly expanding field. The journal serves a crucial role for the publication of information from a wide range of disciplines and is a central outlet for the publication of high-quality peer-reviewed original papers, review articles and short communications. The journal is intentionally interdisciplinary in regard to contributions and covers the following subjects - polymers, environmentally degradable polymers, and degradation pathways: biological, photochemical, oxidative and hydrolytic; new environmental materials: derived by chemical and biosynthetic routes; environmental blends and composites; developments in processing and reactive processing of environmental polymers; characterization of environmental materials: mechanical, physical, thermal, rheological, morphological, and others; recyclable polymers and plastics recycling environmental testing: in-laboratory simulations, outdoor exposures, and standardization of methodologies; environmental fate: end products and intermediates of biodegradation; microbiology and enzymology of polymer biodegradation; solid-waste management and public legislation specific to environmental polymers; and other related topics.
期刊最新文献
Graphene Derivatives Functionalized Polycaprolactone/Gelatin Electrospun Nanofibrous Membrane Through Mussel-Inspired Polydopamine: Multifunctional Scaffold with High Potential for Nerve Tissue Engineering Volatile Compounds and Off-odors Analysis of Recycled PLA for Packaging Applications: An Essential Factor for Ensuring Food Safety and Quality Construction of Magnetic Ag3PO4/Fe3O4/Chitosan Polymer Composite with Enhanced Visible-light-driven Photocatalytic Activity for the Methylene Blue Dye Degradation Degradation of Cationic Polyacrylamide Flocculants upon Contact with Metal Surfaces During Rheological Measurements Green Synthesis of Silver Nanoparticles Using Cyto-compatible Polymer Derivative of Tara Gum for Gold (III) ion Detection in Water Samples
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1