封面:理想对称化合物的发光和单分子磁特性:近平面三配位镱(III)酰胺的实例(欧洲化学 6/2024)

Dr. Nimisha Jain, Dr. Félix Houard, Rémi Marchal, Marie Cordier, Dr. Boris Le Guennic, Dr. Yan Suffren, Dr. Yann Sarazin, Prof. Kevin Bernot
{"title":"封面:理想对称化合物的发光和单分子磁特性:近平面三配位镱(III)酰胺的实例(欧洲化学 6/2024)","authors":"Dr. Nimisha Jain,&nbsp;Dr. Félix Houard,&nbsp;Rémi Marchal,&nbsp;Marie Cordier,&nbsp;Dr. Boris Le Guennic,&nbsp;Dr. Yan Suffren,&nbsp;Dr. Yann Sarazin,&nbsp;Prof. Kevin Bernot","doi":"10.1002/ceur.202480601","DOIUrl":null,"url":null,"abstract":"<p><b>The Front Cover</b> shows a magnetic molecule that is being considered for nanoscale information storage and quantum applications. An ideal molecule based on a tri-coordinated Yb<sup>III</sup> was theorised in 2021. In their Research Article (DOI: 10.1002/ceur.202400062), Y. Sarazin, K. Bernot and co-workers show that this molecule does indeed possess the ideal electronic structure postulated, but that its performance is much weaker than expected. The anomalies observed in its infrared emission could be an experimental signature of active vibronic contributions in the molecule, detrimental to its magnetic behaviour.\n <figure>\n <div><picture>\n <source></source></picture><p></p>\n </div>\n </figure>\n </p>","PeriodicalId":100234,"journal":{"name":"ChemistryEurope","volume":"2 6","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-11-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ceur.202480601","citationCount":"0","resultStr":"{\"title\":\"Front Cover: Luminescence and Single-Molecule Magnet Properties in Ideal Symmetry Compounds: Example of a Near-Planar Tricoordinate Ytterbium(III) Amide (ChemistryEurope 6/2024)\",\"authors\":\"Dr. Nimisha Jain,&nbsp;Dr. Félix Houard,&nbsp;Rémi Marchal,&nbsp;Marie Cordier,&nbsp;Dr. Boris Le Guennic,&nbsp;Dr. Yan Suffren,&nbsp;Dr. Yann Sarazin,&nbsp;Prof. Kevin Bernot\",\"doi\":\"10.1002/ceur.202480601\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><b>The Front Cover</b> shows a magnetic molecule that is being considered for nanoscale information storage and quantum applications. An ideal molecule based on a tri-coordinated Yb<sup>III</sup> was theorised in 2021. In their Research Article (DOI: 10.1002/ceur.202400062), Y. Sarazin, K. Bernot and co-workers show that this molecule does indeed possess the ideal electronic structure postulated, but that its performance is much weaker than expected. The anomalies observed in its infrared emission could be an experimental signature of active vibronic contributions in the molecule, detrimental to its magnetic behaviour.\\n <figure>\\n <div><picture>\\n <source></source></picture><p></p>\\n </div>\\n </figure>\\n </p>\",\"PeriodicalId\":100234,\"journal\":{\"name\":\"ChemistryEurope\",\"volume\":\"2 6\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-11-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ceur.202480601\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ChemistryEurope\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/ceur.202480601\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemistryEurope","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ceur.202480601","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

摘要

封面展示了一种正在考虑用于纳米级信息存储和量子应用的磁性分子。2021 年,一种基于三配位 YbIII 的理想分子被理论化。Y. Sarazin、K. Bernot 及其合作者在他们的研究文章(DOI: 10.1002/ceur.202400062)中表明,这种分子确实具有假设的理想电子结构,但其性能却比预期的要弱得多。在其红外发射中观察到的反常现象可能是分子中活跃的振子贡献的实验特征,不利于其磁性行为。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

摘要图片

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Front Cover: Luminescence and Single-Molecule Magnet Properties in Ideal Symmetry Compounds: Example of a Near-Planar Tricoordinate Ytterbium(III) Amide (ChemistryEurope 6/2024)

The Front Cover shows a magnetic molecule that is being considered for nanoscale information storage and quantum applications. An ideal molecule based on a tri-coordinated YbIII was theorised in 2021. In their Research Article (DOI: 10.1002/ceur.202400062), Y. Sarazin, K. Bernot and co-workers show that this molecule does indeed possess the ideal electronic structure postulated, but that its performance is much weaker than expected. The anomalies observed in its infrared emission could be an experimental signature of active vibronic contributions in the molecule, detrimental to its magnetic behaviour.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
0
期刊最新文献
Front Cover: Luminescence and Single-Molecule Magnet Properties in Ideal Symmetry Compounds: Example of a Near-Planar Tricoordinate Ytterbium(III) Amide (ChemistryEurope 6/2024) Cover Feature: Water Chemistry at the Nanoscale: Clues for Resolving the “Water Paradox” Underlying the Emergence of Life (ChemistryEurope 6/2024) Luminescence and Single-Molecule Magnet Properties in Ideal Symmetry Compounds: Example of a Near-Planar Tricoordinate Ytterbium(III) Amide Steering Photoinduced Electron Transfer in Intramolecular Photocatalysts by Peripheral Ligand Control Water Chemistry at the Nanoscale: Clues for Resolving the “Water Paradox” Underlying the Emergence of Life
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1