Tainára Orlando, Gustavo Henrique Weimer, Paulo Roberto dos Santos Salbego, Alberto Martinez-Cuezva, Jose Berna, Marcos Antonio Pinto Martins
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引用次数: 0
摘要
[2]-或[3]轮烷的稳定性和形成受到螺纹结构微小变化的影响。封面特写描绘了科学家对分子结构的观察，象征着对轮烷分子中组分间相互作用的探索。研究发现，引入第二个大环会略微降低螺纹和第一个大环之间的稳定能，但会显著提高 [3]rotaxane 的整体稳定能。更多信息，请参阅 T. Orlando 及其合作者的研究文章（DOI: 10.1002/chem.202403276）。
Cover Feature: Formation and Stability of Benzylic Amide [2]- and [3]Rotaxanes: An Intercomponent Interactions Study (Chem. Eur. J. 64/2024)
The stability and formation of [2]- or [3]rotaxanes are influenced by minor alterations in the thread structure. The Cover Feature depicts scientists observing the molecular structures, symbolizing the exploration of intercomponent interactions in rotaxane molecules. It has been found that introducing a second macrocycle slightly reduced the stabilization energy between the thread and the first macrocycle but significantly enhanced the overall stabilization energy of the [3]rotaxane. More information can be found in the Research Article by T. Orlando and co-workers (DOI: 10.1002/chem.202403276).
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