{"title":"光催化裂解与胺及其衍生物有关的 C-C 和 C-N 键的最新进展","authors":"Qibo Ni, Yan Zhou, Lang Chen, Yunkui Liu","doi":"10.1039/d4qo02038c","DOIUrl":null,"url":null,"abstract":"The cleavage of C-C and C-N bonds in ubiquitous amines and their derivatives serves as an important and useful protocol for the construction of valuable organic molecules. Recently, the visible-light-driven photocatalytic strategy for the C-C and C-N bond scissions has received much attention because such strategy has characteristic advantages of mild reaction conditions, unique selectivities and environmentally benign operations in comparison with the traditional thermal reaction protocols. In this review, the recent advances in the visible-light-mediated photocatalytic cleavage of C-C and C-N bond associated with amines and their derivatives are summarized. At the end of this review, the limitations and challenges in this field are pointed out, and the future research direction of this field is also prospected.","PeriodicalId":97,"journal":{"name":"Organic Chemistry Frontiers","volume":"38 1","pages":""},"PeriodicalIF":4.6000,"publicationDate":"2024-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Recent advances in the photocatalytic cleavage of C–C and C–N bonds associated with amines and their derivatives\",\"authors\":\"Qibo Ni, Yan Zhou, Lang Chen, Yunkui Liu\",\"doi\":\"10.1039/d4qo02038c\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The cleavage of C-C and C-N bonds in ubiquitous amines and their derivatives serves as an important and useful protocol for the construction of valuable organic molecules. Recently, the visible-light-driven photocatalytic strategy for the C-C and C-N bond scissions has received much attention because such strategy has characteristic advantages of mild reaction conditions, unique selectivities and environmentally benign operations in comparison with the traditional thermal reaction protocols. In this review, the recent advances in the visible-light-mediated photocatalytic cleavage of C-C and C-N bond associated with amines and their derivatives are summarized. At the end of this review, the limitations and challenges in this field are pointed out, and the future research direction of this field is also prospected.\",\"PeriodicalId\":97,\"journal\":{\"name\":\"Organic Chemistry Frontiers\",\"volume\":\"38 1\",\"pages\":\"\"},\"PeriodicalIF\":4.6000,\"publicationDate\":\"2024-11-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Organic Chemistry Frontiers\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1039/d4qo02038c\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, ORGANIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Organic Chemistry Frontiers","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d4qo02038c","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
Recent advances in the photocatalytic cleavage of C–C and C–N bonds associated with amines and their derivatives
The cleavage of C-C and C-N bonds in ubiquitous amines and their derivatives serves as an important and useful protocol for the construction of valuable organic molecules. Recently, the visible-light-driven photocatalytic strategy for the C-C and C-N bond scissions has received much attention because such strategy has characteristic advantages of mild reaction conditions, unique selectivities and environmentally benign operations in comparison with the traditional thermal reaction protocols. In this review, the recent advances in the visible-light-mediated photocatalytic cleavage of C-C and C-N bond associated with amines and their derivatives are summarized. At the end of this review, the limitations and challenges in this field are pointed out, and the future research direction of this field is also prospected.
期刊介绍:
Organic Chemistry Frontiers is an esteemed journal that publishes high-quality research across the field of organic chemistry. It places a significant emphasis on studies that contribute substantially to the field by introducing new or significantly improved protocols and methodologies. The journal covers a wide array of topics which include, but are not limited to, organic synthesis, the development of synthetic methodologies, catalysis, natural products, functional organic materials, supramolecular and macromolecular chemistry, as well as physical and computational organic chemistry.