研究和开发基于金属有机框架 (MOF) 的锂离子和钠离子电池技术

IF 3.5 3区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Journal of Materials Science Pub Date : 2024-11-15 DOI:10.1007/s10853-024-10431-y
Shijie Yuan, Lianghong Dai, Mingfa Xie, Jinyuan Liu, Hongjian Peng
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引用次数: 0

摘要

锂离子电池以其优异的性能成为电子工业的重要组成部分,但随着时代的发展,锂离子电池也逐渐暴露出一些缺点。在此,钠离子电池以其丰富的钠储量和安全低成本的特点,成为商用锂离子电池的潜在替代品。作为各种民用和军用设备的电源,它们受到了科研界的广泛关注。然而,目前锂离子电池和钠离子电池都存在电极能量密度低、循环效率差等问题。正是这些缺陷导致了目前电池应用现状的不足。无独有偶,金属有机框架具有比表面积大、化学结构灵活、易于改性等特点,已被广泛应用于气体吸收、药物载体、传感器等领域。其衍生物作为电池电极材料也被广泛报道。本文综述了金属有机框架及其衍生物(氧化物、硒化物、磷化物和多孔碳)在锂离子电池和钠离子电池中的各种应用现状。最后,简要说明了它们的局限性和未来的改进方法。
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Research and development of lithium and sodium ion battery technology based on metal organic frameworks (MOFs)

Lithium–ion batteries have become a vital component of the electronic industry due to their excellent performance, but with the development of the times, they have gradually revealed some shortcomings. Here, sodium–ion batteries have become a potential alternative to commercial lithium–ion batteries due to their abundant sodium reserves and safe and low-cost characteristics. As power sources for various civilian and military equipment, they have received widespread attention from the scientific research community. However, currently both lithium–ion batteries and sodium–ion batteries have encountered some problems like low electrode energy density and poor cycling efficiency. It is precisely these shortcomings that lead to the current application status of batteries being inadequate. Coincidentally, metal organic frameworks have the characteristics of high surface area, flexible chemical structure, and easy modification, and have been widely used in fields such as gas absorption, drug carriers, and sensors. Its derivatives have also been widely reported as electrode materials for batteries. This article reviews the various application status of metal organic frameworks and their derivatives (oxides, selenides, phosphides and porous carbon) in lithium–ion batteries and sodium–ion batteries. Finally, their limitations and future improvement methods were briefly explained.

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来源期刊
Journal of Materials Science
Journal of Materials Science 工程技术-材料科学:综合
CiteScore
7.90
自引率
4.40%
发文量
1297
审稿时长
2.4 months
期刊介绍: The Journal of Materials Science publishes reviews, full-length papers, and short Communications recording original research results on, or techniques for studying the relationship between structure, properties, and uses of materials. The subjects are seen from international and interdisciplinary perspectives covering areas including metals, ceramics, glasses, polymers, electrical materials, composite materials, fibers, nanostructured materials, nanocomposites, and biological and biomedical materials. The Journal of Materials Science is now firmly established as the leading source of primary communication for scientists investigating the structure and properties of all engineering materials.
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