Buckled-layer K1.39Mn3O6: a novel cathode for potassium-ion batteries

A novel buckled-layer K1.39Mn3O6 cathode was synthesized, featuring P2-oxygen stacking and P3-K sites. The presence of two independent manganese sites significantly influences the charge distribution and diffusion pathways of potassium ions during the charge and discharge processes, resulting in exceptional electrochemical performance. A reversible capacity of 105 mA h g⁻¹ at 100 mA g⁻¹ and remarkable rate capability of 70 mA h g⁻¹ at 1 A g⁻¹ were achieved, surpassing most previously reported KMO cathodes. The findings facilitate the development of innovative cathode materials.