纳米碳粉对高铝浓度凝胶推进剂系统特性的影响。

IF 2.8 2区 化学 Q3 CHEMISTRY, PHYSICAL The Journal of Physical Chemistry B Pub Date : 2024-11-25 DOI:10.1021/acs.jpcb.4c04430
Jiyuan Chen, Hui Zhao, Weifeng Li, Haifeng Liu
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引用次数: 0

摘要

在凝胶推进剂中添加铝颗粒可提高燃料性能,因而备受关注。为了提高凝胶推进剂的能量性能,必须制备高浓度铝的凝胶推进剂。然而,高浓度含铝凝胶遇到了两个挑战。首先,燃烧过程会导致铝颗粒聚集,造成燃烧不完全。此外,高浓度铝颗粒会增加凝胶的粘度,阻碍其雾化过程,进而影响燃烧效率。上述问题给高浓度含铝凝胶推进剂的应用带来了实际障碍。本研究在高浓度含铝凝胶配方中添加了纳米碳粉。通过研究纳米碳对凝胶各种性能的影响,分析了其解决上述问题的潜力。对与碳粉混合的含铝凝胶燃烧性能的研究表明,在凝胶体系中添加 10 wt % 的纳米碳粉可使凝胶推进剂的体积热值显著提高 21.21%。这种提高不仅改善了能量性能,还解决了与铝有关的不完全燃烧问题。对凝胶进行的流变学实验表明,添加纳米碳粉后,凝胶在较低剪切速率下的粘度增加,从而增强了其在储存过程中抵御外部干扰的能力。此外,纳米碳粉的加入还增强了凝胶的剪切稀化特性,使其在较高剪切速率下的粘度显著降低,并使凝胶体系更容易雾化。总之,纳米碳粉的加入可以优化凝胶的储存、雾化和燃烧过程,为提高金属化凝胶推进剂的实用性能提供了一种直接而有效的方法。
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The Impact of Nanocarbon Powder on the Characteristics of a Gel Propellant System with a High Concentration of Aluminum.

The addition of aluminum particles to a gel propellant has garnered attention through its potential for enhancing fuel properties. In order to enhance the energy performance of gel propellants, it is imperative to prepare gel propellants with high concentrations of aluminum. However, high-concentration aluminum-containing gels encounter two challenges. First, the combustion process leads to the agglomeration of aluminum particles, resulting in incomplete combustion. Additionally, elevated concentrations of aluminum particles increase the viscosity of the gel, impeding its atomization process and, subsequently, affecting combustion efficiency. These aforementioned issues pose practical obstacles for the application of high-concentration aluminum-containing gel propellants. In this research, a high-concentration aluminum-containing gel formulation was supplemented with nanocarbon powder. By investigating the impact of nanocarbon on various properties of the gel, its potential for addressing the above issues was analyzed. The investigation into the combustion performance of aluminum-containing gel blended with carbon powder revealed that the addition of 10 wt % nanocarbon powder to the gel system leads to a significant increase in the volumetric calorific value of the gel propellant by 21.21%. This enhancement not only improves the energy performance but also addresses the issue of incomplete combustion associated with aluminum. The rheology experiments conducted on gels demonstrate that the addition of nanocarbon powder results in an increased viscosity of the gel at lower shear rates, thereby enhancing its ability to withstand external disturbances during storage. Furthermore, this incorporation also enhances the gel's shear thinning properties, leading to a significant reduction in viscosity at higher shear rates and facilitating easier atomization of the gel system. In summary, the incorporation of nanocarbon powder can optimize the storage, atomization, and combustion processes of the gel, offering a straightforward and efficient approach to enhance the practical performance of metallized gel propellants.

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来源期刊
CiteScore
5.80
自引率
9.10%
发文量
965
审稿时长
1.6 months
期刊介绍: An essential criterion for acceptance of research articles in the journal is that they provide new physical insight. Please refer to the New Physical Insights virtual issue on what constitutes new physical insight. Manuscripts that are essentially reporting data or applications of data are, in general, not suitable for publication in JPC B.
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