{"title":"Na2Al2B2O7:M (M = Dy3+ 和 Sm3+) 的合成与发光特性","authors":"İlhan Pekgözlü","doi":"10.1007/s10812-024-01826-5","DOIUrl":null,"url":null,"abstract":"<p>Dy<sup>3+</sup>- and Sm<sup>3+</sup>-doped Na<sub>2</sub>Al<sub>2</sub>B<sub>2</sub>O<sub>7</sub> phosphors were synthesized at 850°C for 6 h in air. The phase analyses of all prepared borates were carried out using powder X-ray diffraction (XRD). A spectrofluorometer was used to examine the photoluminescence (PL) characteristics of the prepared phosphors at room temperature. When excited at 350 nm, Na<sub>2</sub>Al<sub>2</sub>B<sub>2</sub>O<sub>7</sub>:Dy<sup>3+</sup> radiates at 481–491, 575–583, and 673 nm. After being excited at 402 nm, Na<sub>2</sub>Al<sub>2</sub>B<sub>2</sub>O<sub>7</sub>:Sm<sup>3+</sup> radiates at 561, 603, 650, and 709 nm. As a result of this study, two new optical materials that emit light in the visible region were prepared.</p>","PeriodicalId":609,"journal":{"name":"Journal of Applied Spectroscopy","volume":"91 5","pages":"1105 - 1109"},"PeriodicalIF":0.8000,"publicationDate":"2024-11-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Luminescence Properties of Na2Al2B2O7:M (M = Dy3+ and Sm3+)\",\"authors\":\"İlhan Pekgözlü\",\"doi\":\"10.1007/s10812-024-01826-5\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Dy<sup>3+</sup>- and Sm<sup>3+</sup>-doped Na<sub>2</sub>Al<sub>2</sub>B<sub>2</sub>O<sub>7</sub> phosphors were synthesized at 850°C for 6 h in air. The phase analyses of all prepared borates were carried out using powder X-ray diffraction (XRD). A spectrofluorometer was used to examine the photoluminescence (PL) characteristics of the prepared phosphors at room temperature. When excited at 350 nm, Na<sub>2</sub>Al<sub>2</sub>B<sub>2</sub>O<sub>7</sub>:Dy<sup>3+</sup> radiates at 481–491, 575–583, and 673 nm. After being excited at 402 nm, Na<sub>2</sub>Al<sub>2</sub>B<sub>2</sub>O<sub>7</sub>:Sm<sup>3+</sup> radiates at 561, 603, 650, and 709 nm. As a result of this study, two new optical materials that emit light in the visible region were prepared.</p>\",\"PeriodicalId\":609,\"journal\":{\"name\":\"Journal of Applied Spectroscopy\",\"volume\":\"91 5\",\"pages\":\"1105 - 1109\"},\"PeriodicalIF\":0.8000,\"publicationDate\":\"2024-11-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Applied Spectroscopy\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10812-024-01826-5\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"SPECTROSCOPY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Applied Spectroscopy","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10812-024-01826-5","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"SPECTROSCOPY","Score":null,"Total":0}
Synthesis and Luminescence Properties of Na2Al2B2O7:M (M = Dy3+ and Sm3+)
Dy3+- and Sm3+-doped Na2Al2B2O7 phosphors were synthesized at 850°C for 6 h in air. The phase analyses of all prepared borates were carried out using powder X-ray diffraction (XRD). A spectrofluorometer was used to examine the photoluminescence (PL) characteristics of the prepared phosphors at room temperature. When excited at 350 nm, Na2Al2B2O7:Dy3+ radiates at 481–491, 575–583, and 673 nm. After being excited at 402 nm, Na2Al2B2O7:Sm3+ radiates at 561, 603, 650, and 709 nm. As a result of this study, two new optical materials that emit light in the visible region were prepared.
期刊介绍:
Journal of Applied Spectroscopy reports on many key applications of spectroscopy in chemistry, physics, metallurgy, and biology. An increasing number of papers focus on the theory of lasers, as well as the tremendous potential for the practical applications of lasers in numerous fields and industries.