Isabel Pérez-Martínez , Ruth Esther Villanueva-Estrada , Claudio Inguaggiato , Mario Alberto Hernández-Hernández , Giovanni Sosa-Ceballos
{"title":"墨西哥中部 Araró-Simirao 地热系统的流体来源","authors":"Isabel Pérez-Martínez , Ruth Esther Villanueva-Estrada , Claudio Inguaggiato , Mario Alberto Hernández-Hernández , Giovanni Sosa-Ceballos","doi":"10.1016/j.gexplo.2024.107637","DOIUrl":null,"url":null,"abstract":"<div><div>The Araró-Simirao geothermal system is located in the eastern part of Cuitzeo Lake in Michoacán, Mexico. It is a liquid-dominated convective system featuring a high salinity, rapid discharge, and heat loss derived into a self-sealing process. The reservoir temperature is higher than 200 °C, associated with a fracture zone linked to the Araró-Simirao fault. Samples of thermal fluids (water and gases) were collected from springs, wells, a mud pool, and runoff water in the study area. The waters had temperatures ranging from 31 °C and 76 °C and near-neutral pH values. Three hydrogeochemical facies types were identified, Na<sup>+</sup>- Cl<sup>−</sup>, Ca<sup>2+</sup>-Na<sup>+</sup> - HCO<sub>3</sub><sup>−</sup>, and Na<sup>+</sup> -HCO<sub>3</sub><sup>−</sup>, associated with deep thermal water, groundwater, and recently infiltrated water, respectively.</div><div>According to the stable isotopes systematics, a binary mixture of thermal water and groundwater was calculated at a proportion from 61 % to 80 % of the thermal component. In the mud pool sample, the chemical composition of bubbling gas is CO<sub>2</sub>-dominated, with a mostly magmatic origin according to the Rc/Ra (5.19), CO<sub>2</sub>/<sup>3</sup>He (4.12 × 10<sup>9</sup>) ratios, and the isotopic composition of δ<sup>13</sup>C<sub>(CO2)</sub> (−8 ‰). The gases dissolved in waters are characterized by higher N<sub>2</sub> and CO<sub>2</sub> concentrations compared to the other gases, representing possible mixing processes between an end-member enriched in CO<sub>2</sub> and the chemical composition of air-saturated water. Regarding helium isotopes, the gases are the result of mixing origins between crustal, atmospheric, and mantellic helium, and 3 groups were identified: 1) high contribution of mantle helium ranging from 21 to 66 % up to (Mud pool, LS07 and LS07A) 2) high contribution of crustal helium (LSA-02, LSA-08A, Araró) ranging from 55 to 80 % and 3) high contribution of atmospheric helium of 84 % (LSA-08). The δ<sup>13</sup>C<sub>(CO2)</sub> results show a primary interaction with magmatic environments and a slightly sedimentary origin. The origin of CO<sub>2</sub>, MORB-type, as well as other gases, may be similar to that in Los Azufres. However, these gases reach the surface through different vertical paths, resulting in varying fluid compositions. In the study area, the Araró-Simirao and Huigo faults would act as zones for these gas ascents from the degassing source (magma) at depth.</div><div>According to the estimates of the magma aging model, the age of the mud pool sample is estimated to be 2.7 × 10<sup>6</sup> ± 1.2 × 10<sup>6</sup> years, which is younger than the andesitic basement rocks. Additionally, there is evidence of a more recent <sup>3</sup>He input in the sample. However, the Los Azufres geothermal system has a <sup>3</sup>He input from rocks that are even younger (1.5 × 10<sup>5</sup> years). This suggests that Los Azufres may have a more recent <sup>3</sup>He input than Araro-Simirao.</div></div>","PeriodicalId":16336,"journal":{"name":"Journal of Geochemical Exploration","volume":"269 ","pages":"Article 107637"},"PeriodicalIF":3.4000,"publicationDate":"2024-11-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Origin of fluids in the Araró-Simirao geothermal system, Central Mexico\",\"authors\":\"Isabel Pérez-Martínez , Ruth Esther Villanueva-Estrada , Claudio Inguaggiato , Mario Alberto Hernández-Hernández , Giovanni Sosa-Ceballos\",\"doi\":\"10.1016/j.gexplo.2024.107637\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The Araró-Simirao geothermal system is located in the eastern part of Cuitzeo Lake in Michoacán, Mexico. It is a liquid-dominated convective system featuring a high salinity, rapid discharge, and heat loss derived into a self-sealing process. The reservoir temperature is higher than 200 °C, associated with a fracture zone linked to the Araró-Simirao fault. Samples of thermal fluids (water and gases) were collected from springs, wells, a mud pool, and runoff water in the study area. The waters had temperatures ranging from 31 °C and 76 °C and near-neutral pH values. Three hydrogeochemical facies types were identified, Na<sup>+</sup>- Cl<sup>−</sup>, Ca<sup>2+</sup>-Na<sup>+</sup> - HCO<sub>3</sub><sup>−</sup>, and Na<sup>+</sup> -HCO<sub>3</sub><sup>−</sup>, associated with deep thermal water, groundwater, and recently infiltrated water, respectively.</div><div>According to the stable isotopes systematics, a binary mixture of thermal water and groundwater was calculated at a proportion from 61 % to 80 % of the thermal component. In the mud pool sample, the chemical composition of bubbling gas is CO<sub>2</sub>-dominated, with a mostly magmatic origin according to the Rc/Ra (5.19), CO<sub>2</sub>/<sup>3</sup>He (4.12 × 10<sup>9</sup>) ratios, and the isotopic composition of δ<sup>13</sup>C<sub>(CO2)</sub> (−8 ‰). The gases dissolved in waters are characterized by higher N<sub>2</sub> and CO<sub>2</sub> concentrations compared to the other gases, representing possible mixing processes between an end-member enriched in CO<sub>2</sub> and the chemical composition of air-saturated water. Regarding helium isotopes, the gases are the result of mixing origins between crustal, atmospheric, and mantellic helium, and 3 groups were identified: 1) high contribution of mantle helium ranging from 21 to 66 % up to (Mud pool, LS07 and LS07A) 2) high contribution of crustal helium (LSA-02, LSA-08A, Araró) ranging from 55 to 80 % and 3) high contribution of atmospheric helium of 84 % (LSA-08). The δ<sup>13</sup>C<sub>(CO2)</sub> results show a primary interaction with magmatic environments and a slightly sedimentary origin. The origin of CO<sub>2</sub>, MORB-type, as well as other gases, may be similar to that in Los Azufres. However, these gases reach the surface through different vertical paths, resulting in varying fluid compositions. In the study area, the Araró-Simirao and Huigo faults would act as zones for these gas ascents from the degassing source (magma) at depth.</div><div>According to the estimates of the magma aging model, the age of the mud pool sample is estimated to be 2.7 × 10<sup>6</sup> ± 1.2 × 10<sup>6</sup> years, which is younger than the andesitic basement rocks. Additionally, there is evidence of a more recent <sup>3</sup>He input in the sample. However, the Los Azufres geothermal system has a <sup>3</sup>He input from rocks that are even younger (1.5 × 10<sup>5</sup> years). This suggests that Los Azufres may have a more recent <sup>3</sup>He input than Araro-Simirao.</div></div>\",\"PeriodicalId\":16336,\"journal\":{\"name\":\"Journal of Geochemical Exploration\",\"volume\":\"269 \",\"pages\":\"Article 107637\"},\"PeriodicalIF\":3.4000,\"publicationDate\":\"2024-11-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Geochemical Exploration\",\"FirstCategoryId\":\"89\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S037567422400253X\",\"RegionNum\":2,\"RegionCategory\":\"地球科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"GEOCHEMISTRY & GEOPHYSICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Geochemical Exploration","FirstCategoryId":"89","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S037567422400253X","RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"GEOCHEMISTRY & GEOPHYSICS","Score":null,"Total":0}
Origin of fluids in the Araró-Simirao geothermal system, Central Mexico
The Araró-Simirao geothermal system is located in the eastern part of Cuitzeo Lake in Michoacán, Mexico. It is a liquid-dominated convective system featuring a high salinity, rapid discharge, and heat loss derived into a self-sealing process. The reservoir temperature is higher than 200 °C, associated with a fracture zone linked to the Araró-Simirao fault. Samples of thermal fluids (water and gases) were collected from springs, wells, a mud pool, and runoff water in the study area. The waters had temperatures ranging from 31 °C and 76 °C and near-neutral pH values. Three hydrogeochemical facies types were identified, Na+- Cl−, Ca2+-Na+ - HCO3−, and Na+ -HCO3−, associated with deep thermal water, groundwater, and recently infiltrated water, respectively.
According to the stable isotopes systematics, a binary mixture of thermal water and groundwater was calculated at a proportion from 61 % to 80 % of the thermal component. In the mud pool sample, the chemical composition of bubbling gas is CO2-dominated, with a mostly magmatic origin according to the Rc/Ra (5.19), CO2/3He (4.12 × 109) ratios, and the isotopic composition of δ13C(CO2) (−8 ‰). The gases dissolved in waters are characterized by higher N2 and CO2 concentrations compared to the other gases, representing possible mixing processes between an end-member enriched in CO2 and the chemical composition of air-saturated water. Regarding helium isotopes, the gases are the result of mixing origins between crustal, atmospheric, and mantellic helium, and 3 groups were identified: 1) high contribution of mantle helium ranging from 21 to 66 % up to (Mud pool, LS07 and LS07A) 2) high contribution of crustal helium (LSA-02, LSA-08A, Araró) ranging from 55 to 80 % and 3) high contribution of atmospheric helium of 84 % (LSA-08). The δ13C(CO2) results show a primary interaction with magmatic environments and a slightly sedimentary origin. The origin of CO2, MORB-type, as well as other gases, may be similar to that in Los Azufres. However, these gases reach the surface through different vertical paths, resulting in varying fluid compositions. In the study area, the Araró-Simirao and Huigo faults would act as zones for these gas ascents from the degassing source (magma) at depth.
According to the estimates of the magma aging model, the age of the mud pool sample is estimated to be 2.7 × 106 ± 1.2 × 106 years, which is younger than the andesitic basement rocks. Additionally, there is evidence of a more recent 3He input in the sample. However, the Los Azufres geothermal system has a 3He input from rocks that are even younger (1.5 × 105 years). This suggests that Los Azufres may have a more recent 3He input than Araro-Simirao.
期刊介绍:
Journal of Geochemical Exploration is mostly dedicated to publication of original studies in exploration and environmental geochemistry and related topics.
Contributions considered of prevalent interest for the journal include researches based on the application of innovative methods to:
define the genesis and the evolution of mineral deposits including transfer of elements in large-scale mineralized areas.
analyze complex systems at the boundaries between bio-geochemistry, metal transport and mineral accumulation.
evaluate effects of historical mining activities on the surface environment.
trace pollutant sources and define their fate and transport models in the near-surface and surface environments involving solid, fluid and aerial matrices.
assess and quantify natural and technogenic radioactivity in the environment.
determine geochemical anomalies and set baseline reference values using compositional data analysis, multivariate statistics and geo-spatial analysis.
assess the impacts of anthropogenic contamination on ecosystems and human health at local and regional scale to prioritize and classify risks through deterministic and stochastic approaches.
Papers dedicated to the presentation of newly developed methods in analytical geochemistry to be applied in the field or in laboratory are also within the topics of interest for the journal.