HAT光氧化还原催化多组分合成吲哚- 4h -铬

IF 2.1 3区 化学 Q2 CHEMISTRY, ORGANIC Tetrahedron Pub Date : 2024-11-26 DOI:10.1016/j.tet.2024.134386
Shraddha Tivari , Mohd Zaheeruddin Beg , Akanksha Kashyap , Pravin K. Singh , Praveen P. Singh , Sudhanshu Kanaujia , Vishal Srivastava
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引用次数: 0

摘要

报道了水杨醛、二美酮和吲哚在可见光诱导下光氧化还原合成吲哚- 4h -铬的无金属多组分反应。这种新方法涉及利用可见光通过同时反应生成吲哚- 4h -铬,该反应涉及C-O和C-C键的形成,在非常温和的反应条件下获得所需产物的显着产率。这种一锅合成方法具有底物范围广、起始材料易得、效率高等优点。
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Photoredox catalyzed multi component synthesis of indolyl-4H-chromenes via HAT
Visible light-induced photoredox catalyzed, metal-free multicomponent reaction among salicylaldehydes, dimedone and indoles for synthesis of Indolyl-4H-chromenes has been reported. This new approach involving the use of visible light to form Indolyl-4H-chromenes through simultaneous reaction which involves C–O and C–C bonds formation with significant yield of the desired product in remarkably moderate reaction conditions. This one-pot synthetic method has many advantages, including a wide range of substrates, readily available starting materials and high efficiency.
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来源期刊
Tetrahedron
Tetrahedron 化学-有机化学
CiteScore
3.90
自引率
4.80%
发文量
439
审稿时长
34 days
期刊介绍: Tetrahedron publishes full accounts of research having outstanding significance in the broad field of organic chemistry and its related disciplines, such as organic materials and bio-organic chemistry. Regular papers in Tetrahedron are expected to represent detailed accounts of an original study having substantially greater scope and details than that found in a communication, as published in Tetrahedron Letters. Tetrahedron also publishes thematic collections of papers as special issues and ''Reports'', commissioned in-depth reviews providing a comprehensive overview of a research area.
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