Efficient Light-Driven Ion Pumping for Deep Desalination via the Vertical Gradient Protonation of Covalent Organic Framework Membranes.

Traditional desalination methods face criticism due to high energy requirements and inadequate trace ion removal, whereas natural light-driven ion pumps offer superior efficiency. Current synthetic systems are constrained by short exciton lifetimes, which limit their ability to generate sufficient electric fields for effective ion pumping. We introduce an innovative approach utilizing covalent-organic framework membranes that enhance light absorption and reduce charge recombination through vertical gradient protonation of imine linkages during acid-catalyzed liquid-liquid interfacial polymerization. This technique creates intralayer and interlayer heterojunctions, facilitating interlayer hybridization and establishing a robust built-in electric field under illumination. These improvements enable the membranes to achieve remarkable ion transport across extreme concentration gradients (2000:1), with a transport rate of approximately 3.2 × 10¹² ions per second per square centimeter and reduce ion concentrations to parts per billion. This performance significantly surpasses that of conventional reverse osmosis systems, representing a major advancement in solar-powered desalination technology by substantially reducing energy consumption and secondary waste.