Xue-Ting Wang, Fang-Wen Lv, Hang Qin, Xin-Tong Dai, Shan Jin and Xiu-Ying Zheng
{"title":"通过螺旋组装的手性镧系链的圆极化放大发光","authors":"Xue-Ting Wang, Fang-Wen Lv, Hang Qin, Xin-Tong Dai, Shan Jin and Xiu-Ying Zheng","doi":"10.1039/D4CE00957F","DOIUrl":null,"url":null,"abstract":"<p >Accurately designing and controlling the synthesis of circularly polarized luminescent (CPL) materials with both large asymmetry factor (<em>g</em><small><sub>lum</sub></small>) and high quantum yield (<em>Φ</em><small><sub>lum</sub></small>) values is a key scientific challenge. In this study, chiral ligands and luminescent π-conjugated systems are utilized as mixed ligands to form chiral helical polymers <strong><em>R</em>/<em>S</em>-Ln-phen</strong> (Ln = Eu/Tb) by the regulation of intramolecular and intermolecular interactions. This approach aims to amplify the chirality and enhance luminescence efficiency. The compounds <strong><em>R</em>/<em>S</em>-Eu-phen</strong> and <strong><em>R</em>/<em>S</em>-Tb-phen</strong> demonstrated extremely high <em>Φ</em><small><sub>lum</sub></small> (86.88% for <strong><em>R</em>/<em>S</em>-Eu-phen</strong> and 88.93% for <strong><em>R</em>/<em>S</em>-Tb-phen</strong>) and relatively large <em>g</em><small><sub>lum</sub></small> (≈10<small><sup>−3</sup></small>) values.</p>","PeriodicalId":70,"journal":{"name":"CrystEngComm","volume":" 47","pages":" 6676-6682"},"PeriodicalIF":2.4000,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Amplified circularly polarized luminescence of chiral lanthanide-based chains through helical assembly†\",\"authors\":\"Xue-Ting Wang, Fang-Wen Lv, Hang Qin, Xin-Tong Dai, Shan Jin and Xiu-Ying Zheng\",\"doi\":\"10.1039/D4CE00957F\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Accurately designing and controlling the synthesis of circularly polarized luminescent (CPL) materials with both large asymmetry factor (<em>g</em><small><sub>lum</sub></small>) and high quantum yield (<em>Φ</em><small><sub>lum</sub></small>) values is a key scientific challenge. In this study, chiral ligands and luminescent π-conjugated systems are utilized as mixed ligands to form chiral helical polymers <strong><em>R</em>/<em>S</em>-Ln-phen</strong> (Ln = Eu/Tb) by the regulation of intramolecular and intermolecular interactions. This approach aims to amplify the chirality and enhance luminescence efficiency. The compounds <strong><em>R</em>/<em>S</em>-Eu-phen</strong> and <strong><em>R</em>/<em>S</em>-Tb-phen</strong> demonstrated extremely high <em>Φ</em><small><sub>lum</sub></small> (86.88% for <strong><em>R</em>/<em>S</em>-Eu-phen</strong> and 88.93% for <strong><em>R</em>/<em>S</em>-Tb-phen</strong>) and relatively large <em>g</em><small><sub>lum</sub></small> (≈10<small><sup>−3</sup></small>) values.</p>\",\"PeriodicalId\":70,\"journal\":{\"name\":\"CrystEngComm\",\"volume\":\" 47\",\"pages\":\" 6676-6682\"},\"PeriodicalIF\":2.4000,\"publicationDate\":\"2024-10-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"CrystEngComm\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2024/ce/d4ce00957f\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"CrystEngComm","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/ce/d4ce00957f","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
精确设计和控制具有大不对称系数（glum）和高量子产率（Φlum）值的圆偏振发光（CPL）材料的合成是一个关键的科学挑战。本研究利用手性配体和发光π共轭体系作为混合配体，通过调节分子内和分子间的相互作用，形成了手性螺旋聚合物R/S-Ln-phen （Ln = Eu/Tb）。该方法旨在增强手性和提高发光效率。化合物R/ s - eul -phen和R/S-Tb-phen具有极高的Φlum值（R/ s - eul -phen为86.88%，R/S-Tb-phen为88.93%）和较大的glum值（≈10−3）。
Amplified circularly polarized luminescence of chiral lanthanide-based chains through helical assembly†
Accurately designing and controlling the synthesis of circularly polarized luminescent (CPL) materials with both large asymmetry factor (glum) and high quantum yield (Φlum) values is a key scientific challenge. In this study, chiral ligands and luminescent π-conjugated systems are utilized as mixed ligands to form chiral helical polymers R/S-Ln-phen (Ln = Eu/Tb) by the regulation of intramolecular and intermolecular interactions. This approach aims to amplify the chirality and enhance luminescence efficiency. The compounds R/S-Eu-phen and R/S-Tb-phen demonstrated extremely high Φlum (86.88% for R/S-Eu-phen and 88.93% for R/S-Tb-phen) and relatively large glum (≈10−3) values.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
