Nitrogen-containing organic aerosols and highly oxidized molecules produced by reaction of ozone with floor cleaning detergent†

Cleaning detergents are a source of numerous volatile organic compounds (VOCs) which are highly reactive towards ozone leading to the formation of secondary organic aerosols (SOA) in indoor environments. Here we perform real-time measurements of the organic composition of aerosols produced upon ozone reaction with floor cleaning detergent by extractive electrospray ionization time-of-flight mass spectrometer (EESI-TOF-MS) coupled to a chamber reactor. The experiments were performed in the absence of light and under light irradiation (320 nm < λ < 400 nm) simulating the fraction of sunlight that penetrates indoors. The multiple increases in particle number concentrations correspond to rise in the signal intensity of specific species. Notably, the secondary increase in particle mass concentration is mainly contributed by highly oxidized molecules (HOMs), which increased from 16.5% upon ozone oxidation to 19.9% under photo-oxidation reactions. A large fraction of CHON compounds such as imidazole, pyrazine/pyrimidine, and azaindole was observed most likely formed through the reaction of O₃ with benzothiazole (constituent of the cleaning detergent). The difference between the molecular compositions detected in the absence of light and in the presence of light indicates that sunlight penetrating through the windows can affect the SOA produced by the reaction of ozone with the floor cleaning detergent.