三氯化（三苯基膦-κP）钴酸（II）苯。

IUCrData Pub Date : 2024-11-01 DOI:10.1107/S2414314624011210

Lubabalo Ndima , Eric Cyriel Hosten , Richard Betz

{"title":"三氯化（三苯基膦-κP）钴酸（II）苯。","authors":"Lubabalo Ndima , Eric Cyriel Hosten , Richard Betz","doi":"10.1107/S2414314624011210","DOIUrl":null,"url":null,"abstract":"<div><div>The central atom of the complex anion is coordinated by one triphenylphosphane and three chlorido ligands. The negative charge is balanced by a triphenylphosphonium cation. Two benzene solvent molecules are also present in the asymmetric unit.</div></div><div><div>The solvated title compound, (C<sub>18</sub>H<sub>16</sub>P)[CoCl<sub>3</sub>(C<sub>18</sub>H<sub>15</sub>P)]·2C<sub>6</sub>H<sub>6</sub>, is the triphenylphosphonium salt of an anionic Co<sup>II</sup> chlorido coordination compound; the asymmetric unit features an ion-pair and two benzene solvent molecules. One of the solvent molecules shows rotational disorder. C—H⋯Cl and P—H⋯Cl contacts connect the individual constituents into infinite chains extending parallel to [010].<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (406KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"9 11","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11618865/pdf/","citationCount":"0","resultStr":"{\"title\":\"Triphenylphosphonium trichlorido(triphenylphosphane-κP)cobaltate(II) benzene disolvate\",\"authors\":\"Lubabalo Ndima , Eric Cyriel Hosten , Richard Betz\",\"doi\":\"10.1107/S2414314624011210\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>The central atom of the complex anion is coordinated by one triphenylphosphane and three chlorido ligands. The negative charge is balanced by a triphenylphosphonium cation. Two benzene solvent molecules are also present in the asymmetric unit.</div></div><div><div>The solvated title compound, (C<sub>18</sub>H<sub>16</sub>P)[CoCl<sub>3</sub>(C<sub>18</sub>H<sub>15</sub>P)]·2C<sub>6</sub>H<sub>6</sub>, is the triphenylphosphonium salt of an anionic Co<sup>II</sup> chlorido coordination compound; the asymmetric unit features an ion-pair and two benzene solvent molecules. One of the solvent molecules shows rotational disorder. C—H⋯Cl and P—H⋯Cl contacts connect the individual constituents into infinite chains extending parallel to [010].<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (406KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>\",\"PeriodicalId\":94324,\"journal\":{\"name\":\"IUCrData\",\"volume\":\"9 11\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-11-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11618865/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"IUCrData\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S241431462400107X\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S241431462400107X","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}

引用次数: 0

摘要

溶剂化后的标题化合物（C18H16P）[CoCl3(C18H15P)]·2C6H6是阴离子CoII氯基配位化合物的三苯基磷酸盐；不对称单元具有一个离子对和两个苯溶剂分子。其中一个溶剂分子表现出旋转无序。C-H⋯Cl和P-H⋯Cl触点将单个组分连接成平行于[010]的无限链。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

Triphenylphosphonium trichlorido(triphenylphosphane-κP)cobaltate(II) benzene disolvate

The central atom of the complex anion is coordinated by one triphenylphosphane and three chlorido ligands. The negative charge is balanced by a triphenylphosphonium cation. Two benzene solvent molecules are also present in the asymmetric unit.

The solvated title compound, (C₁₈H₁₆P)[CoCl₃(C₁₈H₁₅P)]·2C₆H₆, is the triphenylphosphonium salt of an anionic Co^II chlorido coordination compound; the asymmetric unit features an ion-pair and two benzene solvent molecules. One of the solvent molecules shows rotational disorder. C—H⋯Cl and P—H⋯Cl contacts connect the individual constituents into infinite chains extending parallel to [010].

Download: Download high-res image (406KB)
Download: Download full-size image

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊