{"title":"Tri-phenyl-phospho-nium tri-chlorido-(tri-phenyl-phosphane-κ<i>P</i>)cobaltate(II) benzene disolvate.","authors":"Lubabalo Ndima, Eric Cyriel Hosten, Richard Betz","doi":"10.1107/S2414314624011210","DOIUrl":null,"url":null,"abstract":"<p><p>The solvated title compound, (C<sub>18</sub>H<sub>16</sub>P)[CoCl<sub>3</sub>(C<sub>18</sub>H<sub>15</sub>P)]·2C<sub>6</sub>H<sub>6</sub>, is the tri-phenyl-phospho-nium salt of an anionic Co<sup>II</sup> chlorido coordination compound; the asymmetric unit features an ion-pair and two benzene solvent molecules. One of the solvent mol-ecules shows rotational disorder. C-H⋯Cl and P-H⋯Cl contacts connect the individual constituents into infinite chains extending parallel to [010].</p>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"9 Pt 11","pages":"x241121"},"PeriodicalIF":0.0000,"publicationDate":"2024-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11618865/pdf/","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1107/S2414314624011210","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/11/1 0:00:00","PubModel":"eCollection","JCR":"","JCRName":"","Score":null,"Total":0}
The solvated title compound, (C18H16P)[CoCl3(C18H15P)]·2C6H6, is the tri-phenyl-phospho-nium salt of an anionic CoII chlorido coordination compound; the asymmetric unit features an ion-pair and two benzene solvent molecules. One of the solvent mol-ecules shows rotational disorder. C-H⋯Cl and P-H⋯Cl contacts connect the individual constituents into infinite chains extending parallel to [010].
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