磷酸三(4-chloro-phen-yl)。

IUCrData Pub Date : 2024-11-01 DOI:10.1107/S2414314624010617

Joshua Birch , Eric Cyriel Hosten , Richard Betz

{"title":"磷酸三(4-chloro-phen-yl)。","authors":"Joshua Birch , Eric Cyriel Hosten , Richard Betz","doi":"10.1107/S2414314624010617","DOIUrl":null,"url":null,"abstract":"<div><div>In the title compound, the symmetric phosphate derived from <em>para</em>-chlorophenol and phosphoric acid, two of the three aromatic moieties adopt <em>syn</em>-orientation towards the P=O bond while the last chlorophenol ring is pointing away from this bond. In the extended structure, C—H⋯O bonds connect the individual molecules into sheets lying perpendicular to the crystallographic <em>b</em> axis.</div></div><div><div>The title compound, C<sub>18</sub>H<sub>12</sub>Cl<sub>3</sub>O<sub>4</sub>P, is the symmetric phosphate derived from <em>para</em>-chlorophenol and phosphoric acid. Two of the three aromatic moieties adopt <em>syn</em>-orientation towards the P=O bond while the last chlorophenol ring is pointing away from this bond. In the extended structure, C—H⋯O bonds connect the individual molecules into sheets lying perpendicular to the crystallographic <em>b</em> axis.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (197KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"9 11","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11618868/pdf/","citationCount":"0","resultStr":"{\"title\":\"Tris(4-chlorophenyl) phosphate\",\"authors\":\"Joshua Birch , Eric Cyriel Hosten , Richard Betz\",\"doi\":\"10.1107/S2414314624010617\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>In the title compound, the symmetric phosphate derived from <em>para</em>-chlorophenol and phosphoric acid, two of the three aromatic moieties adopt <em>syn</em>-orientation towards the P=O bond while the last chlorophenol ring is pointing away from this bond. In the extended structure, C—H⋯O bonds connect the individual molecules into sheets lying perpendicular to the crystallographic <em>b</em> axis.</div></div><div><div>The title compound, C<sub>18</sub>H<sub>12</sub>Cl<sub>3</sub>O<sub>4</sub>P, is the symmetric phosphate derived from <em>para</em>-chlorophenol and phosphoric acid. Two of the three aromatic moieties adopt <em>syn</em>-orientation towards the P=O bond while the last chlorophenol ring is pointing away from this bond. In the extended structure, C—H⋯O bonds connect the individual molecules into sheets lying perpendicular to the crystallographic <em>b</em> axis.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (197KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>\",\"PeriodicalId\":94324,\"journal\":{\"name\":\"IUCrData\",\"volume\":\"9 11\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-11-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11618868/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"IUCrData\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S2414314624001068\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2414314624001068","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}

引用次数: 0

摘要

标题化合物C18H12Cl3O4P是由对氯苯酚和磷酸合成的对称磷酸。三个芳香基团中有两个对着P=O键，而最后一个氯酚环则指向P=O键。在扩展结构中，C-H⋯O键将单个分子连接成垂直于晶体学b轴的薄片。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

Tris(4-chlorophenyl) phosphate

In the title compound, the symmetric phosphate derived from para-chlorophenol and phosphoric acid, two of the three aromatic moieties adopt syn-orientation towards the P=O bond while the last chlorophenol ring is pointing away from this bond. In the extended structure, C—H⋯O bonds connect the individual molecules into sheets lying perpendicular to the crystallographic b axis.

The title compound, C₁₈H₁₂Cl₃O₄P, is the symmetric phosphate derived from para-chlorophenol and phosphoric acid. Two of the three aromatic moieties adopt syn-orientation towards the P=O bond while the last chlorophenol ring is pointing away from this bond. In the extended structure, C—H⋯O bonds connect the individual molecules into sheets lying perpendicular to the crystallographic b axis.

Download: Download high-res image (197KB)
Download: Download full-size image

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊