Irina A. Shentseva, Andrey N. Usoltsev, Nikita A. Korobeynikov, Maxim N. Sokolov and Sergey A. Adonin
{"title":"一维异金属Bi/Ag和Sb/Ag溴金属酸盐（iii）：结构、热稳定性和光学性质†","authors":"Irina A. Shentseva, Andrey N. Usoltsev, Nikita A. Korobeynikov, Maxim N. Sokolov and Sergey A. Adonin","doi":"10.1039/D4CE01083C","DOIUrl":null,"url":null,"abstract":"<p >Silver-containing heterometallic bromobismuthates(<small>III</small>) (3-BrPyC<small><sub>3</sub></small>){[BiAgBr<small><sub>6</sub></small>]} (<strong>1</strong>) and (ImC<small><sub>4</sub></small>){[BiAgBr<small><sub>6</sub></small>]} (<strong>2</strong>) and bromoantimonate (ImC<small><sub>4</sub></small>)<small><sub>3</sub></small>{[Sb<small><sub>3</sub></small>Ag<small><sub>2</sub></small>Br<small><sub>17</sub></small>]} (<strong>3</strong>) (3-BrPyC<small><sub>3</sub></small> – 1,6-bis(3-bromopyridin-1-ium)propane dication, ImC<small><sub>4</sub></small> – diprotonated 1,4-bis(1<em>H</em>-imidazol-1-yl)butane) were synthesized. All compounds are composed of infinite chains, featuring yet unprecedented in halometalate(<small>III</small>) chemistry structural types. <strong>1–3</strong> reveal relatively high (>200 °C) thermal stability. Optical band gaps for <strong>1–3</strong> were estimated from UV-vis spectroscopy data.</p>","PeriodicalId":70,"journal":{"name":"CrystEngComm","volume":" 48","pages":" 6823-6827"},"PeriodicalIF":2.6000,"publicationDate":"2024-11-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"One-dimensional heterometallic Bi/Ag and Sb/Ag bromometalates(iii): structures, thermal stability and optical properties†\",\"authors\":\"Irina A. Shentseva, Andrey N. Usoltsev, Nikita A. Korobeynikov, Maxim N. Sokolov and Sergey A. Adonin\",\"doi\":\"10.1039/D4CE01083C\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Silver-containing heterometallic bromobismuthates(<small>III</small>) (3-BrPyC<small><sub>3</sub></small>){[BiAgBr<small><sub>6</sub></small>]} (<strong>1</strong>) and (ImC<small><sub>4</sub></small>){[BiAgBr<small><sub>6</sub></small>]} (<strong>2</strong>) and bromoantimonate (ImC<small><sub>4</sub></small>)<small><sub>3</sub></small>{[Sb<small><sub>3</sub></small>Ag<small><sub>2</sub></small>Br<small><sub>17</sub></small>]} (<strong>3</strong>) (3-BrPyC<small><sub>3</sub></small> – 1,6-bis(3-bromopyridin-1-ium)propane dication, ImC<small><sub>4</sub></small> – diprotonated 1,4-bis(1<em>H</em>-imidazol-1-yl)butane) were synthesized. All compounds are composed of infinite chains, featuring yet unprecedented in halometalate(<small>III</small>) chemistry structural types. <strong>1–3</strong> reveal relatively high (>200 °C) thermal stability. Optical band gaps for <strong>1–3</strong> were estimated from UV-vis spectroscopy data.</p>\",\"PeriodicalId\":70,\"journal\":{\"name\":\"CrystEngComm\",\"volume\":\" 48\",\"pages\":\" 6823-6827\"},\"PeriodicalIF\":2.6000,\"publicationDate\":\"2024-11-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"CrystEngComm\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2024/ce/d4ce01083c\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"CrystEngComm","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/ce/d4ce01083c","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
One-dimensional heterometallic Bi/Ag and Sb/Ag bromometalates(iii): structures, thermal stability and optical properties†
Silver-containing heterometallic bromobismuthates(III) (3-BrPyC3){[BiAgBr6]} (1) and (ImC4){[BiAgBr6]} (2) and bromoantimonate (ImC4)3{[Sb3Ag2Br17]} (3) (3-BrPyC3 – 1,6-bis(3-bromopyridin-1-ium)propane dication, ImC4 – diprotonated 1,4-bis(1H-imidazol-1-yl)butane) were synthesized. All compounds are composed of infinite chains, featuring yet unprecedented in halometalate(III) chemistry structural types. 1–3 reveal relatively high (>200 °C) thermal stability. Optical band gaps for 1–3 were estimated from UV-vis spectroscopy data.
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