高温PEMFC通道水滴曲线挡板的设计与优化

IF 2.6 4区 化学 Q3 CHEMISTRY, PHYSICAL Ionics Pub Date : 2024-09-29 DOI:10.1007/s11581-024-05853-2
Hao Yang, Taihong Cheng, Yi Mao
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引用次数: 0

摘要

高温质子交换膜燃料电池(HT-PEMFC)的工作温度超过120℃。在HT-PEMFC流道中策略性地添加挡板,可以促进反应物气体向气体扩散层(GDL)扩散,增加催化层的反应面积,提高反应速率,提高整体性能。与以往的折流板设计相比,本文提出的水滴曲线折流板具有更优的气流曲率分布。本研究采用三维仿真建模与遗传算法优化相结合的方法,对水滴曲线挡板的最优数量、进出口方向和尺寸参数进行了研究。对HT-PEMFC中0到4个挡板配置的净功率密度进行了比较,结果表明,有4个挡板的配置具有更好的性能,净功率密度为0.368 W/cm2,与没有挡板的基本通道相比增加了5.74%。此外,与正流相比,反向流动产生的额外压降为1.12%。优化后,将变量设置为a = 0.730123, b = 0.317671,净功率密度增加到0.3759 W/cm2,比未优化状态提高2.17%,从而达到HT-PEMFC的最佳性能水平。
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Design and optimization of water drop curve baffles in high temperature PEMFC channel

The operating temperature of high-temperature proton exchange membrane fuel cells (HT-PEMFC) exceeds 120 °C. The strategic addition of baffles in the HT-PEMFC flow channel can facilitate the diffusion of reactant gases towards the gas diffusion layer (GDL), increase the reaction area of the catalytic layer, improve the reaction rate, and enhance overall performance. The water drops curve baffle proposed in this study exhibits a more optimal curvature profile for gas flow compared to previous baffle designs. In this study, the optimal quantity, inlet and outlet orientations, and size parameters of the water drop curve baffles were examined by combining three-dimensional simulation modeling with genetic algorithm optimization. A comparison of net power density for configurations ranging from zero to four baffles in the HT-PEMFC demonstrated that the configuration with four baffles achieved superior performance, resulting in a net power density of 0.368 W/cm2, which represents a 5.74% increase compared to the basic channel without baffles. Additionally, it was observed that reverse flow incurs an additional pressure drop of 1.12% compared to forward flow. Following optimization, with the variables set to a = 0.730123 and b = 0.317671, the net power density increased to 0.3759 W/cm2, reflecting a 2.17% improvement over the non-optimized state, thereby achieving the optimal performance level for HT-PEMFC.

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来源期刊
Ionics
Ionics 化学-电化学
CiteScore
5.30
自引率
7.10%
发文量
427
审稿时长
2.2 months
期刊介绍: Ionics is publishing original results in the fields of science and technology of ionic motion. This includes theoretical, experimental and practical work on electrolytes, electrode, ionic/electronic interfaces, ionic transport aspects of corrosion, galvanic cells, e.g. for thermodynamic and kinetic studies, batteries, fuel cells, sensors and electrochromics. Fast solid ionic conductors are presently providing new opportunities in view of several advantages, in addition to conventional liquid electrolytes.
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