CuFe2O4/CuO@rGO三元复合材料的优化及其作为超级电容器电极材料的电化学评价

IF 2.6 4区 化学 Q3 CHEMISTRY, PHYSICAL Ionics Pub Date : 2024-10-07 DOI:10.1007/s11581-024-05866-x
R. Gayathri, R. Sharmila, S. Vadivel, Mohammad Shahzad Samdani
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引用次数: 0

摘要

本文采用水热法制备了CuFe₂O₄/CuO@rGO纳米复合材料。为了研究这些纳米复合材料的电化学性能,研究人员构建了双电极和三电极结构。纳米复合材料CuFe₂O₄/CuO@rGO在1 A/g下的比电容达到2110 F/g。在功率密度为780 Wkg - 1时,以活性炭(AC)为负极,CuFe₂O₄/CuO@ rGO为正极,该非对称电容器表现出40.44 Wh kg - 1的能量密度。它还具有较长的循环寿命,在10,000次循环后保持93%的保留率。通过照亮发光二极管(LED)灯,不对称电池展示了这种纳米复合材料作为活性电极材料的实际用途。该装置通过保持恒定的电化学活性证明了其结构耐久性。据我们所知,合成的纳米复合材料表现出优异的性能。所生产的纳米复合材料令人印象深刻的电化学能力使其成为高性能混合电容器中有吸引力的电极。
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Optimisation of a ternary composite of CuFe2O4/CuO@rGO and its electrochemical evaluation as an electrode material for supercapacitor applications

In this study, CuFe₂O₄/CuO@rGO nanocomposites were prepared using the hydrothermal technique. In order to investigate these nanocomposite electrochemical properties, researchers constructed two-electrode and three-electrode configurations. The nanocomposite CuFe₂O₄/CuO@rGO showed an impressive specific capacitance of 2110 F/g at 1 A/g. This asymmetric capacitor showed an impressive 40.44 Wh kg−1 energy density at a power density of 780 Wkg−1, with activated carbon (AC) as the negative electrode and CuFe₂O₄/CuO@ rGO as the positive electrode. It also had a prolonged cycle life, with 93% retention after 10,000 cycles. By illuminating light-emitting diode (LED) lights, the asymmetric cell demonstrated the practical use of this nanocomposite as an active electrode material. This device demonstrated its structural durability by maintaining a constant electrochemical activity. To our knowledge, the synthesised nanocomposite demonstrated superior performance. The impressive electrochemical capability of the produced nanocomposite makes it an attractive electrode for use in high-performance hybrid capacitors.

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来源期刊
Ionics
Ionics 化学-电化学
CiteScore
5.30
自引率
7.10%
发文量
427
审稿时长
2.2 months
期刊介绍: Ionics is publishing original results in the fields of science and technology of ionic motion. This includes theoretical, experimental and practical work on electrolytes, electrode, ionic/electronic interfaces, ionic transport aspects of corrosion, galvanic cells, e.g. for thermodynamic and kinetic studies, batteries, fuel cells, sensors and electrochromics. Fast solid ionic conductors are presently providing new opportunities in view of several advantages, in addition to conventional liquid electrolytes.
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