利用酞菁辅助空穴传输材料增强高性能钙钛矿太阳能电池的空穴提取和转移

IF 7.1 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY ACS Sustainable Chemistry & Engineering Pub Date : 2024-12-12 DOI:10.1021/acssuschemeng.4c07524
Min Xu, Liangding Zheng, Peng Wang, Shihuai Wang, Lin Xie, Yong Hua
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引用次数: 0

摘要

为了实现优异的钙钛矿太阳能电池性能,迫切需要加强空穴的提取和空穴传输层(HTL)的转移。本文将一种新型酞菁(TQ)引入到Spiro-OMeTAD中,对HTL的空穴输运特性进行了精细优化,以获得更好的性能。结果表明,TQ掺入可以有效地增强器件中的空穴提取/转移,减少电荷复合。经过tq处理的器件的功率转换效率从21.91%提高到24.29%。值得注意的是,这些未封装的器件表现出非凡的水分、光和热稳定性。
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Enhancing Hole Extraction and Transfer via Phthalocyanine-Assisted Hole Transport Material for High-Performance Perovskite Solar Cells
Enhancing hole extraction and transfer of the hole transport layer (HTL) is urgently needed to achieve excellent performance perovskite solar cells. Herein, a novel phthalocyanine (TQ) has been introduced into Spiro-OMeTAD to finely optimize the hole transport properties of the HTL for achieving better performance. It is demonstrated that TQ incorporation can effectively enhance hole extraction/transfer and reduce charge recombination in the device. The TQ-treated device yields an improved power conversion efficiency of 24.29% from 21.91%. Remarkably, these unencapsulated devices demonstrate remarkable moisture, light, and thermal stabilities.
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来源期刊
ACS Sustainable Chemistry & Engineering
ACS Sustainable Chemistry & Engineering CHEMISTRY, MULTIDISCIPLINARY-ENGINEERING, CHEMICAL
CiteScore
13.80
自引率
4.80%
发文量
1470
审稿时长
1.7 months
期刊介绍: ACS Sustainable Chemistry & Engineering is a prestigious weekly peer-reviewed scientific journal published by the American Chemical Society. Dedicated to advancing the principles of green chemistry and green engineering, it covers a wide array of research topics including green chemistry, green engineering, biomass, alternative energy, and life cycle assessment. The journal welcomes submissions in various formats, including Letters, Articles, Features, and Perspectives (Reviews), that address the challenges of sustainability in the chemical enterprise and contribute to the advancement of sustainable practices. Join us in shaping the future of sustainable chemistry and engineering.
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