在氮化介质中通过气相转化从冶金联合企业二次废物中提取锰和铬

IF 0.7 4区 工程技术 Q4 ENGINEERING, CHEMICAL Theoretical Foundations of Chemical Engineering Pub Date : 2024-12-16 DOI:10.1134/S0040579524700647
S. A. Kulyukhin, Yu. M. Nevolin, A. F. Seliverstov
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引用次数: 0

摘要

提出了在HNO3(蒸汽)-空气或NOx-H2O(蒸汽)-空气气氛中对二次废物进行气相处理,并用水进一步浸出Mn和Cr的方法,用于从冶金厂(诺里尔斯克联合企业选矿厂的飞灰和古巴国有商业加勒比镍公司Punda Gourda镍生产联合企业的废石)的二次废物中提取Mn和Cr。结果表明,在400-425 K的渗氮气氛中对二次废物进行初步处理5 h,可以从二次废物的体积中浸出Mn。对于诺里尔斯克联合选矿厂的飞灰和古巴国有加勒比商业镍公司邦达古尔达镍生产联合厂的废石,水提Mn的比例分别小于其总含量的33%和65%。Cr的萃取度均小于2%。
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Mn and Cr Extraction from the Secondary Wastes of Metallurgical Combines by Gas-Phase Conversion in Nitriding Media

An approach based on the gas-phase processing of secondary wastes in an HNO3 (vapor)–air or NOx–H2O (vapor)–air atmosphere with further Mn and Cr leaching with water is proposed for Mn and Cr extraction from the secondary wastes of metallurgical plants (fly ash from the ore-dressing plant of the Norilsk Combine and rock refuses from the Punda Gourda Nickel Production Combine of the Cuban State-Owned Commercial Caribbean Nickel Company). It is shown that the preliminary treatment of secondary wastes in a nitriding atmosphere at a temperature of 400–425 K for 5 h makes it possible to leach Mn from the volume of secondary wastes. For the fly ash from the ore-dressing plant of the Norilsk Combine and the rock refuses from the Punda Gourda Nickel Production Combine of the Cuban State-Owned Commercial Caribbean Nickel Company, the degree of Mn extraction with water is less than ~33 and ~65% of their total content in the wastes, respectively. The degree of Cr extraction is less ~2% in all cases.

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来源期刊
CiteScore
1.20
自引率
25.00%
发文量
70
审稿时长
24 months
期刊介绍: Theoretical Foundations of Chemical Engineering is a comprehensive journal covering all aspects of theoretical and applied research in chemical engineering, including transport phenomena; surface phenomena; processes of mixture separation; theory and methods of chemical reactor design; combined processes and multifunctional reactors; hydromechanic, thermal, diffusion, and chemical processes and apparatus, membrane processes and reactors; biotechnology; dispersed systems; nanotechnologies; process intensification; information modeling and analysis; energy- and resource-saving processes; environmentally clean processes and technologies.
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